JEE Main 2024 (Online) 5th April Morning Shift
JEE Main / 90 questions
2026Fri, Apr 5, 2024 3:30 AM90 PYQs
1Alcohols Phenols And Ethers
Given below are two statement :
Statements I : Bromination of phenol in solvent with low polarity such as \(\mathrm{CHCl}_3\) or \(\mathrm{CS}_2\) requires Lewis acid catalyst.
Statements II : The Lewis acid catalyst polarises the bromine t...
Statements I : Bromination of phenol in solvent with low polarity such as \(\mathrm{CHCl}_3\) or \(\mathrm{CS}_2\) requires Lewis acid catalyst.
Statements II : The Lewis acid catalyst polarises the bromine t...
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2Alcohols Phenols And Ethers
For the Compounds :
(A) \(\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{O}-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_3\)
(B) \(\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_3\)
(C)
(D)
The increasing order of...
(A) \(\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{O}-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_3\)
(B) \(\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_3\)
(C)
(D)
The increasing order of...
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3Alcohols Phenols And Ethers
Consider the given chemical reaction sequence :
Total sum of oxygen atoms in Product A and Product B are ________.
Total sum of oxygen atoms in Product A and Product B are ________.
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4Aldehydes Ketones And Carboxylic Acids
Identify 'A' in the following reaction :
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5Basics Of Organic Chemistry
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Cis form of alkene is found to be more polar than the trans form.
Reason (R) : Dipole moment of trans isomer of 2-but...
Assertion (A) : Cis form of alkene is found to be more polar than the trans form.
Reason (R) : Dipole moment of trans isomer of 2-but...
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6Biomolecules
Which of the following gives a positive test with ninhydrin ?
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7Chemical Bonding And Molecular Structure
In the lewis dot structure for \(\mathrm{NO}_2^{-}\), total number of valence electrons around nitrogen is _________.
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8Chemical Bonding And Molecular Structure
Number of \(\sigma\) and \(\pi\) bonds present in ethylene molecule is respectively :
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9Chemical Equilibrium
The following reaction occurs in the Blast furnance where iron ore is reduced to iron metal
\(\mathrm{Fe}_2 \mathrm{O}_{3(s)}+3 \mathrm{CO}_{(g)} \rightleftharpoons \mathrm{Fe}_{(\mathrm{l})}+3 \mathrm{CO}_{2(g)}\)
Using the Le-chatelier's ...
\(\mathrm{Fe}_2 \mathrm{O}_{3(s)}+3 \mathrm{CO}_{(g)} \rightleftharpoons \mathrm{Fe}_{(\mathrm{l})}+3 \mathrm{CO}_{2(g)}\)
Using the Le-chatelier's ...
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10Chemical Kinetics And Nuclear Chemistry
During Kinetic study of reaction \(\mathrm{2 A+B \rightarrow C+D}\), the following results were obtained :
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11Compounds Containing Nitrogen
\(9.3 \mathrm{~g}\) of pure aniline is treated with bromine water at room temperature to give a white precipitate of the product '\(\mathrm{P}\)'. The mass of product '\(\mathrm{P}\)' obtained is \(26.4 \mathrm{~g}\). The percentage yield i...
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12Compounds Containing Nitrogen
Identify compound (Z) in the following reaction sequence.
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13Coordination Compounds
Which one of the following complexes will exhibit the least paramagnetic behaviour ?
[Atomic number, \(\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27\)]
[Atomic number, \(\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27\)]
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14Coordination Compounds
The spin-only magnetic moment value of the ion among \(\mathrm{Ti}^{2+}, \mathrm{V}^{2+}, \mathrm{Co}^{3+}\) and \(\mathrm{Cr}^{2+}\), that acts as strong oxidising agent in aqueous solution is _________ BM (Near integer).
(Given atomic num...
(Given atomic num...
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15Coordination Compounds
The correct order of ligands arranged in increasing field strength.
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16D And F Block Elements
The metal that shows highest and maximum number of oxidation state is :
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17D And F Block Elements
In a borax bead test under hot condition, a metal salt (one from the given) is heated at point B of the flame, resulted in green colour salt bead. The spin-only magnetic moment value of the salt is _______ BM (Nearest integer) [Given atomi...
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18Electrochemistry
The reaction at cathode in the cells commonly used in clocks involves.
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19Electrochemistry
Molar ionic conductivities of divalent cation and anion are \(57 \mathrm{~S~cm}^2 \mathrm{~mol}^{-1}\) and \(73 \mathrm{~S~cm}^2 \mathrm{~mol}^{-1}\) respectively. The molar conductivity of solution of an electrolyte with the above cation a...
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20Haloalkanes And Haloarenes
The number of halobenzenes from the following that can be prepared by Sandmeyer's reaction is _________
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21Hydrocarbons
Given below are two statements :
Statement I :
Nitration of benzene involves the following step -
Statement II : Use of Lewis base promotes the electrophilic substitution of benzene.
In the light of the above statements, choose the most ap...
Statement I :
Nitration of benzene involves the following step -
Statement II : Use of Lewis base promotes the electrophilic substitution of benzene.
In the light of the above statements, choose the most ap...
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22P Block Elements
The number of neutrons present in the more abundant isotope of boron is '\(x\)'. Amorphous boron upon heating with air forms a product, in which the oxidation state of boron is '\(y\)'. The value of \(x+y\) is _________ .
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23Periodic Table And Periodicity
The statement(s) that are correct about the species \(\mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Na}^{+}\) and \(\mathrm{Mg}^{2+}\).
(A) All are isoelectronic
(B) All have the same nuclear charge
(C) \(\mathrm{O}^{2-}\) has the largest ionic ...
(A) All are isoelectronic
(B) All have the same nuclear charge
(C) \(\mathrm{O}^{2-}\) has the largest ionic ...
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24Periodic Table And Periodicity
Given below are two statements:
Statement I: In group 13, the stability of +1 oxidation state increases down the group.
Statement II : The atomic size of gallium is greater than that of aluminium.
In the light of the above statements, choos...
Statement I: In group 13, the stability of +1 oxidation state increases down the group.
Statement II : The atomic size of gallium is greater than that of aluminium.
In the light of the above statements, choos...
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25Solutions
An artificial cell is made by encapsulating \(0.2 \mathrm{~M}\) glucose solution within a semipermeable membrane. The osmotic pressure developed when the artificial cell is placed within a \(0.05 \mathrm{~M}\) solution of \(\mathrm{NaCl}\) ...
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26Some Basic Concepts Of Chemistry
An organic compound has \(42.1 \%\) carbon, \(6.4 \%\) hydrogen and remainder is oxygen. If its molecular weight is 342 , then its molecular formula is :
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27Structure Of Atom
The incorrect postulates of the Dalton's atomic theory are :
(A) Atoms of different elements differ in mass.
(B) Matter consists of divisible atoms.
(C) Compounds are formed when atoms of different element combine in a fixed ratio.
(D) All ...
(A) Atoms of different elements differ in mass.
(B) Matter consists of divisible atoms.
(C) Compounds are formed when atoms of different element combine in a fixed ratio.
(D) All ...
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28Structure Of Atom
The value of Rydberg constant \((R_H)\) is \(2.18 \times 10^{-18} \mathrm{~J}\). The velocity of electron having mass \(9.1 \times 10^{-31} \mathrm{~kg}\) in Bohr's first orbit of hydrogen atom = ________ \(\times 10^5 \mathrm{~ms}^{-1}\) (...
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29Thermodynamics
The heat of combustion of solid benzoic acid at constant volume is \(-321.30 \mathrm{~kJ}\) at \(27^{\circ} \mathrm{C}\). The heat of combustion at constant pressure is \((-321.30-x \mathrm{R}) \mathrm{~kJ}\), the value of \(x\) is ________...
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30Thermodynamics
Given below are two statements: One is labelled as Assertion (A) and the other is labelled as Reason (R)
Assertion (A) : Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always $$-57 \mathrm{~kJ} \mathrm{~m...
Assertion (A) : Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always $$-57 \mathrm{~kJ} \mathrm{~m...
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313d Geometry
Let \(\mathrm{d}\) be the distance of the point of intersection of the lines \(\frac{x+6}{3}=\frac{y}{2}=\frac{z+1}{1}\) and \(\frac{x-7}{4}=\frac{y-9}{3}=\frac{z-4}{2}\) from the point \((7,8,9)\). Then \(\mathrm{d}^2+6\) is equal to :
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323d Geometry
If the line \(\frac{2-x}{3}=\frac{3 y-2}{4 \lambda+1}=4-z\) makes a right angle with the line \(\frac{x+3}{3 \mu}=\frac{1-2 y}{6}=\frac{5-z}{7}\), then \(4 \lambda+9 \mu\) is equal to :
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33Application Of Derivatives
For the function
\(f(x)=\sin x+3 x-\frac{2}{\pi}\left(x^2+x\right), \text { where } x \in\left[0, \frac{\pi}{2}\right],\)
consider the following two statements :
(I) \(f\) is increasing in \(\left(0, \frac{\pi}{2}\right)\).
(II) $$f^{\prime...
\(f(x)=\sin x+3 x-\frac{2}{\pi}\left(x^2+x\right), \text { where } x \in\left[0, \frac{\pi}{2}\right],\)
consider the following two statements :
(I) \(f\) is increasing in \(\left(0, \frac{\pi}{2}\right)\).
(II) $$f^{\prime...
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34Application Of Derivatives
Let a rectangle ABCD of sides 2 and 4 be inscribed in another rectangle PQRS such that the vertices of the rectangle ABCD lie on the sides of the rectangle PQRS. Let a and b be the sides of the rectangle PQRS when its area is maximum. Then ...
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35Application Of Derivatives
Let \(f(x)=x^5+2 x^3+3 x+1, x \in \mathbf{R}\), and \(g(x)\) be a function such that \(g(f(x))=x\) for all \(x \in \mathbf{R}\). Then \(\frac{g(7)}{g^{\prime}(7)}\) is equal to :
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36Area Under The Curves
The area of the region enclosed by the parabolas \(y=x^2-5 x\) and \(y=7 x-x^2\) is ________.
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37Binomial Theorem
If the constant term in the expansion of \(\left(1+2 x-3 x^3\right)\left(\frac{3}{2} x^2-\frac{1}{3 x}\right)^9\) is \(\mathrm{p}\), then \(108 \mathrm{p}\) is equal to ________.
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38Circle
Let a circle C of radius 1 and closer to the origin be such that the lines passing through the point \((3,2)\) and parallel to the coordinate axes touch it. Then the shortest distance of the circle C from the point \((5,5)\) is :
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39Complex Numbers
Consider the following two statements :
Statement I: For any two non-zero complex numbers $$z_1, z_2,(|z_1|+|z_2|)\left|\frac{z_1}{\left|z_1\right|}+\frac{z_2}{\left|z_2\right|}\right| \leq 2\left(\left|z_1\right|+\left|z_2\right|\right) \t...
Statement I: For any two non-zero complex numbers $$z_1, z_2,(|z_1|+|z_2|)\left|\frac{z_1}{\left|z_1\right|}+\frac{z_2}{\left|z_2\right|}\right| \leq 2\left(\left|z_1\right|+\left|z_2\right|\right) \t...
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40Definite Integration
The value of \(\int_\limits{-\pi}^\pi \frac{2 y(1+\sin y)}{1+\cos ^2 y} d y\) is :
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41Definite Integration
The integral \(\int_\limits0^{\pi / 4} \frac{136 \sin x}{3 \sin x+5 \cos x} \mathrm{~d} x\) is equal to :
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42Differential Equations
If \(y=y(x)\) is the solution of the differential equation \(\frac{\mathrm{d} y}{\mathrm{~d} x}+2 y=\sin (2 x), y(0)=\frac{3}{4}\), then \(y\left(\frac{\pi}{8}\right)\) is equal to :
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43Ellipse
Let the line \(2 x+3 y-\mathrm{k}=0, \mathrm{k}>0\), intersect the \(x\)-axis and \(y\)-axis at the points \(\mathrm{A}\) and \(\mathrm{B}\), respectively. If the equation of the circle having the line segment \(A B\) as a diameter is $$x^2...
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44Functions
If \(S=\{a \in \mathbf{R}:|2 a-1|=3[a]+2\{a \}\}\), where \([t]\) denotes the greatest integer less than or equal to \(t\) and \(\{t\}\) represents the fractional part of \(t\), then \(72 \sum_\limits{a \in S} a\) is equal to _________.
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45Functions
Let \(A=\{1,3,7,9,11\}\) and \(B=\{2,4,5,7,8,10,12\}\). Then the total number of one-one maps \(f: A \rightarrow B\), such that \(f(1)+f(3)=14\), is :
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46Limits Continuity And Differentiability
If the function \(f(x)=\frac{\sin 3 x+\alpha \sin x-\beta \cos 3 x}{x^3}, x \in \mathbf{R}\), is continuous at \(x=0\), then \(f(0)\) is equal to :
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47Limits Continuity And Differentiability
Let \(f\) be a differentiable function in the interval \((0, \infty)\) such that \(f(1)=1\) and \(\lim _\limits{t \rightarrow x} \frac{t^2 f(x)-x^2 f(t)}{t-x}=1\) for each \(x>0\). Then \(2 f(2)+3 f(3)\) is equal to _________.
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48Matrices And Determinants
Let A and B be two square matrices of order 3 such that \(\mathrm{|A|=3}\) and \(\mathrm{|B|=2}\). Then $$|\mathrm{A}^{\mathrm{T}} \mathrm{A}(\operatorname{adj}(2 \mathrm{~A}))^{-1}(\operatorname{adj}(4 \mathrm{~B}))(\operatorname{adj}(\mat...
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49Matrices And Determinants
If the system of equations
$$\begin{array}{r} 11 x+y+\lambda z=-5 \\ 2 x+3 y+5 z=3 \\ 8 x-19 y-39 z=\mu \end{array}$$
has infinitely many solutions, then \(\lambda^4-\mu\) is equal to :
$$\begin{array}{r} 11 x+y+\lambda z=-5 \\ 2 x+3 y+5 z=3 \\ 8 x-19 y-39 z=\mu \end{array}$$
has infinitely many solutions, then \(\lambda^4-\mu\) is equal to :
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50Parabola
Suppose \(\mathrm{AB}\) is a focal chord of the parabola \(y^2=12 x\) of length \(l\) and slope \(\mathrm{m}<\sqrt{3}\). If the distance of the chord \(\mathrm{AB}\) from the origin is \(\mathrm{d}\), then \(l \mathrm{~d}^2\) is equal to __...
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