JEE Main 2025 (Online) 8th April Evening Shift
JEE Main / 75 questions
2026Tue, Apr 8, 2025 9:30 AM75 PYQs
1Aldehydes Ketones And Carboxylic Acids
When undergoes intramolecular aldol condensation, the major product formed is :
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2Aldehydes Ketones And Carboxylic Acids
Choose the correct option for structures of $A$ and $B$, respectively
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3Basics Of Organic Chemistry
Match the LIST-I with LIST-II
LIST-I LIST-II A. Carbocation I. Species that can supply a pair of electrons. B. C-Free radical II. Species that can receive a pair of electrons. C. Nucleophile III. sp2 hybridized carbon with empty ...
LIST-I LIST-II A. Carbocation I. Species that can supply a pair of electrons. B. C-Free radical II. Species that can receive a pair of electrons. C. Nucleophile III. sp2 hybridized carbon with empty ...
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4Basics Of Organic Chemistry
What is the correct IUPAC name of the compound?
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5Chemical Equilibrium
The equilibrium constant for decomposition of $\text{H}_2\text{O(g)}$
$ \text{H}_2\text{O(g)} \rightleftharpoons \text{H}_2\text{(g)} + \frac{1}{2}\text{O}_2\text{(g)} \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $
is $8.0 \times 10...
$ \text{H}_2\text{O(g)} \rightleftharpoons \text{H}_2\text{(g)} + \frac{1}{2}\text{O}_2\text{(g)} \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $
is $8.0 \times 10...
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6Chemical Kinetics And Nuclear Chemistry
In a first order decomposition reaction, the time taken for the decomposition of reactant to one fourth and one eighth of its initial concentration are $t_1$ and $t_2$ (s), respectively. The ratio $t_1/t_2$ will be:
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7Compounds Containing Nitrogen
$\mathrm{A} \xrightarrow[\text { (i) } \mathrm{H}_3 \mathrm{O}^{+}]{\text {(i) } \mathrm{NaH}} \mathrm{B} \xrightarrow[\text { (ii) } \mathrm{H}_2 \mathrm{SO}_4, \Delta]{\text { (i) } \mathrm{EOH}} \mathrm{C}$
' A ' shows positive Lassaign'...
' A ' shows positive Lassaign'...
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8Coordination Compounds
Match the LIST-I with LIST-IItable {width: 100%;border-collapse: collapse;margin: 20px 0;}th {background-color: blue;color: white;border: 1px solid lightgrey;padding: 10px;}td {border: 1px solid lightgrey;padding: 10px;text-align: left;}LIS...
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9Coordination Compounds
The number of species from the following that are involved in sp3d2 hybridization is :[Co(NH3)6]3+, SF6, [CrF6]3−, [CoF6]3−, [Mn(CN)6]3−, and [MnCl6]3−
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10Coordination Compounds
Given below are two statements:Statement I: A homoleptic octahedral complex, formed using monodentate ligands, will not show stereoisomerism.Statement II: cis- and trans- platin are heteroleptic complexes of Pd.In the light of the above sta...
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11D And F Block Elements
The correct decreasing order of spin only magnetic moment values (BM) of Cu+, Cu2+, Cr2+ and Cr3+ ions is :
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12Electrochemistry
Consider the following half cell reaction\(\text{Cr}_2\text{O}_7^{2-} \, (\text{aq}) + 6\text{e}^- + 14\text{H}^+ \, (\text{aq}) \rightarrow 2\text{Cr}^{3+} \, (\text{aq}) + 7\text{H}_2\text{O} \, (\ell)\)The reaction was conducted with ...
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13Haloalkanes And Haloarenes
'P' is
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14Haloalkanes And Haloarenes
Choose the correct set of reagents for the following conversion.
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15Haloalkanes And Haloarenes
Which one of the following reactions will not lead to the desired ether formation in major proportion?
(iso- $\mathrm{Bu} \Rightarrow$ isobutyl, sec $-\mathrm{Bu} \Rightarrow$ sec-butyl, $\mathrm{nPr} \Rightarrow \mathrm{n}$-propyl, $$ { }^...
(iso- $\mathrm{Bu} \Rightarrow$ isobutyl, sec $-\mathrm{Bu} \Rightarrow$ sec-butyl, $\mathrm{nPr} \Rightarrow \mathrm{n}$-propyl, $$ { }^...
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16Periodic Table And Periodicity
The atomic number of the element from the following with lowest 1st ionisation enthalpy is :
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17Periodic Table And Periodicity
Given below are two statements:Statement I: H2Se is more acidic than H2TeStatement II: H2Se has higher bond enthalpy for dissociation than H2TeIn the light of the above statements, choose the correct answer from the options given below:
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18Salt Analysis
Match the LIST-I with LIST-IItable {width: 100%;border-collapse: collapse;margin: 20px 0;}th {background-color: blue;color: white;border: 1px solid lightgrey;padding: 10px;}td {border: 1px solid lightgrey;padding: 10px;text-align: left;}LIS...
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19Solutions
$\mathrm{HA}(a q) \rightleftharpoons \mathrm{H}^{+}(a q)+\mathrm{A}^{-}(a q)$The freezing point depression of a 0.1 m aqueous solution of a monobasic weak acid HA is 0.20 °C. The dissociation constant for the acid isGiven: $K_f$(H2O) = 1.8 ...
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20Solutions
Which of the following binary mixture does not show the behaviour of minimum boiling azeotropes?
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21Some Basic Concepts Of Chemistry
On combustion 0.210 g of an organic compound containing C, H and O gave 0.127 g H2O and 0.307 g CO2. The percentages of hydrogen and oxygen in the given organic compound respectively are:
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22Some Basic Concepts Of Chemistry
20 mL of sodium iodide solution gave 4.74 g silver iodide when treated with excess of silver nitrate solution. The molarity of the sodium iodide solution is _______ M. (Nearest Integer value) (Given : Na = 23, I = 127, Ag = 108, N = 14, O =...
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23Structure Of Atom
Correct statements for an element with atomic number 9 are:A. There can be 5 electrons for which $m_s = +\frac{1}{2}$ and 4 electrons for which $m_s = -\frac{1}{2}$.B. There is only one electron in $p_z$ orbital.C. The last electron goes to...
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24Structure Of Atom
The energy of an electron in the first Bohr orbit of the H-atom is -13.6 eV. The magnitude of energy value of an electron in the first excited state of Be3+ is ________ eV (nearest integer value).
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25Thermodynamics
Resonance in $\mathrm{X}_2 \mathrm{Y}$ can be represented as
The enthalpy of formation of $X_2Y$ $ \left(X = X(g) + \frac{1}{2} Y = Y(g) \rightarrow X_2Y(g) \right) $ is 80 kJ mol$^{-1}$. The magnitude of resonance energy of $X_2Y$ is __ kJ...
The enthalpy of formation of $X_2Y$ $ \left(X = X(g) + \frac{1}{2} Y = Y(g) \rightarrow X_2Y(g) \right) $ is 80 kJ mol$^{-1}$. The magnitude of resonance energy of $X_2Y$ is __ kJ...
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263d Geometry
Let the values of $\lambda$ for which the shortest distance between the lines $\frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{4}$
and $\frac{x-\lambda}{3} = \frac{y-4}{4} = \frac{z-5}{5}$ is $\frac{1}{\sqrt{6}}$ be $\lambda_1$ and $\lambda_2$....
and $\frac{x-\lambda}{3} = \frac{y-4}{4} = \frac{z-5}{5}$ is $\frac{1}{\sqrt{6}}$ be $\lambda_1$ and $\lambda_2$....
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273d Geometry
Let the area of the triangle formed by the lines $x+2=y-1=z, \frac{x-3}{5}=\frac{y}{-1}=\frac{z-1}{1}$ and $\frac{x}{-3}=\frac{y-3}{3}=\frac{z-2}{1}$ be $A$. Then $A^2$ is equal to ________.
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28Application Of Derivatives
Let the function $ f(x) = \frac{x}{3} + \frac{3}{x} + 3, x \neq 0 $ be strictly increasing in $(-\infty, \alpha_1) \cup (\alpha_2, \infty)$ and strictly decreasing in $(\alpha_3, \alpha_4) \cup (\alpha_4, \alpha_5)$. Then $ \sum\limits_{i=1...
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29Area Under The Curves
Let the area of the bounded region $\left\{(x, y): 0 \leq 9 x \leq y^2, y \geq 3 x-6\right\}$ be $A$. Then $6 A$ is equal to _________.
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30Binomial Theorem
The number of integral terms in the expansion of $ \left( {5^\frac{1}{2}} + 7^\frac{1}{8} \right)^{1016} $ is:
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31Binomial Theorem
The product of the last two digits of $(1919)^{1919}$ is
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32Complex Numbers
Let $ A = \left\{ \theta \in [0, 2\pi] : 1 + 10\operatorname{Re}\left( \frac{2\cos\theta + i\sin\theta}{\cos\theta - 3i\sin\theta} \right) = 0 \right\} $. Then $ \sum\limits_{\theta \in A} \theta^2 $ is equal to
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33Definite Integration
The integral $\int\limits_{-1}^{\frac{3}{2}} \left(| \pi^2 x \sin(\pi x) \right|) dx$ is equal to:
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34Definite Integration
Let f(x) be a positive function and $I_{1} = \int\limits_{-\frac{1}{2}}^{1} 2x \, f(2x(1-2x)) \, dx$ and $I_{2} = \int\limits_{-1}^{2} f(x(1-x)) \, dx$. Then the value of $\frac{I_{2}}{I_{1}}$ is equal to ________
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35Differential Equations
Let $f(x) = x - 1$ and $g(x) = e^x$ for $x \in \mathbb{R}$. If $\frac{dy}{dx} = \left( e^{-2\sqrt{x}} g\left(f(f(x))\right) - \frac{y}{\sqrt{x}} \right)$, $y(0) = 0$, then $y(1)$ is
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36Ellipse
Let the ellipse $3x^2 + py^2 = 4$ pass through the centre $C$ of the circle $x^2 + y^2 - 2x - 4y - 11 = 0$ of radius $r$. Let $f_1, f_2$ be the focal distances of the point $C$ on the ellipse. Then $6f_1f_2 - r$ is equal to
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37Functions
Let the domain of the function $f(x)=\cos ^{-1}\left(\frac{4 x+5}{3 x-7}\right)$ be $[\alpha, \beta]$ and the domain of $g(x)=\log _2\left(2-6 \log _{27}(2 x+5)\right)$ be $(\gamma, \delta)$.
Then $|7(\alpha+\beta)+4(\gamma+\delta)|$ is equ...
Then $|7(\alpha+\beta)+4(\gamma+\delta)|$ is equ...
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38Inverse Trigonometric Functions
The value of $ \cot^{-1} \left( \frac{\sqrt{1 + \tan^2(2)} - 1}{\tan(2)} \right) - \cot^{-1} \left( \frac{\sqrt{1 + \tan^2\left(\frac{1}{2}\right)} + 1}{\tan\left(\frac{1}{2}\right)} \right) $ is equal to
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39Limits Continuity And Differentiability
Given below are two statements:
Statement I: $ \lim\limits_{x \to 0} \left( \frac{\tan^{-1} x + \log_e \sqrt{\frac{1+x}{1-x}} - 2x}{x^5} \right) = \frac{2}{5} $
Statement II: $ \lim\limits_{x \to 1} \left( x^{\frac{2}{1-x}} \right) = \frac{...
Statement I: $ \lim\limits_{x \to 0} \left( \frac{\tan^{-1} x + \log_e \sqrt{\frac{1+x}{1-x}} - 2x}{x^5} \right) = \frac{2}{5} $
Statement II: $ \lim\limits_{x \to 1} \left( x^{\frac{2}{1-x}} \right) = \frac{...
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40Matrices And Determinants
Let α be a solution of $x^2 + x + 1 = 0$, and for some a and b in $R, \begin{bmatrix} 4 & a & b \end{bmatrix} \begin{bmatrix} 1 & 16 & 13 \\ -1 & -1 & 2 \\ -2 & -14 & -8 \end{bmatrix} = \begin{bmatrix} 0 & 0 & 0 \end{bmatrix}$. If $\frac{4}...
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41Matrices And Determinants
Let $ A = \begin{bmatrix} 2 & 2+p & 2+p+q \\ 4 & 6+2p & 8+3p+2q \\ 6 & 12+3p & 20+6p+3q \end{bmatrix} $.
If $ \det(\text{adj}(\text{adj}(3A))) = 2^m \cdot 3^n $, $ m, n \in \mathbb{N} $, then $ m + n $ is equal to
If $ \det(\text{adj}(\text{adj}(3A))) = 2^m \cdot 3^n $, $ m, n \in \mathbb{N} $, then $ m + n $ is equal to
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42Parabola
Let $r$ be the radius of the circle, which touches $x$ - axis at point $(a, 0), a<0$ and the parabola $\mathrm{y}^2=9 x$ at the point $(4,6)$. Then $r$ is equal to ______.
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43Permutations And Combinations
There are 12 points in a plane, no three of which are in the same straight line, except 5 points which are collinear. Then the total number of triangles that can be formed with the vertices at any three of these 12 points is
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44Probability
If A and B are two events such that $P(A) = 0.7$, $P(B) = 0.4$ and $P(A \cap \overline{B}) = 0.5$, where $\overline{B}$ denotes the complement of B, then $P\left(B \mid (A \cup \overline{B})\right)$ is equal to
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45Quadratic Equation And Inequalities
The sum of the squares of the roots of $ |x-2|^2 + |x-2| - 2 = 0 $ and the squares of the roots of $ x^2 - 2|x-3| - 5 = 0 $, is
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46Sequences And Series
If $ \frac{1}{1^4} + \frac{1}{2^4} + \frac{1}{3^4} + \ldots \infty= \frac{\pi^4}{90} $, $\frac{1}{1^4} + \frac{1}{3^4} + \frac{1}{5^4} + \ldots \infty= \alpha $, $ \frac{1}{2^4} + \frac{1}{4^4} + \frac{1}{6^4} + \ldots \infty= \beta $, then...
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47Sets And Relations
Let A = {0, 1, 2, 3, 4, 5}. Let R be a relation on A defined by (x, y) ∈ R if and only if max{x, y} ∈ {3, 4}. Then among the statements (S1): The number of elements in R is 18, and (S2): The relation R is symmetric but neither reflexive nor...
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48Straight Lines And Pair Of Straight Lines
Let a be the length of a side of a square OABC with O being the origin. Its side OA makes an acute angle \(\alpha\) with the positive x-axis and the equations of its diagonals are $(\sqrt{3}+1)x+(\sqrt{3}-1)y=0$ and $(\sqrt{3}-1)x-(\sqrt{3...
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49Straight Lines And Pair Of Straight Lines
A line passing through the point P($a$, 0) makes an acute angle \(\alpha\) with the positive x-axis. Let this line be rotated about the point P through an angle $\frac{\alpha}{2}$ in the clockwise direction. If in the new position, the slo...
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50Vector Algebra
Let $ \vec{a} = \hat{i} + 2\hat{j} + \hat{k} $ and $ \vec{b} = 2\hat{i} + \hat{j} - \hat{k} $. Let $ \hat{c} $ be a unit vector in the plane of the vectors $ \vec{a} $ and $ \vec{b} $ and be perpendicular to $ \vec{a} $. Then such a vector ...
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