JEE Main 2025 (Online) 29th January Morning Shift
JEE Main / 75 questions
2026Wed, Jan 29, 2025 3:30 AM75 PYQs
1Alcohols Phenols And Ethers
0.1 mole of compound ‘S’ will weigh ___________ g.(Given molar mass in g mol−1 C : 12, H : 1, O : 16)
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2Aldehydes Ketones And Carboxylic Acids
The product (P) formed in the following reaction is :
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3Basics Of Organic Chemistry
Match List - I with List - II.
List - I (Structure)
List - II (IUPAC Name)
(A)
(I) 4-Methylpent-1-ene
(B) (CH3)2C(C3H7)2
(II) 3-Ethyl-5-methylheptane
(C)
(III) 4,4-Dimethylheptane
...
List - I (Structure)
List - II (IUPAC Name)
(A)
(I) 4-Methylpent-1-ene
(B) (CH3)2C(C3H7)2
(II) 3-Ethyl-5-methylheptane
(C)
(III) 4,4-Dimethylheptane
...
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4Basics Of Organic Chemistry
Total number of nucleophiles from the following is :
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5Biomolecules
Match List - I with List - II.
List - I (Carbohydrate)
List - II (Linkage Source)
(A) Amylose
(I) $\beta$ - $C_1 - C_4$, plant
(B) Cellulose
(II) $\alpha$ - $C_1 - C_4$, animal
(C) Glycogen
(III) $\alpha$ - $C_1 - C_4$, $\alpha$ ...
List - I (Carbohydrate)
List - II (Linkage Source)
(A) Amylose
(I) $\beta$ - $C_1 - C_4$, plant
(B) Cellulose
(II) $\alpha$ - $C_1 - C_4$, animal
(C) Glycogen
(III) $\alpha$ - $C_1 - C_4$, $\alpha$ ...
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6Chemical Equilibrium
At temperature T, compound $AB_{2(g)}$ dissociates as $AB_{2(g)} \rightleftharpoons AB_{(g)} + \frac{1}{2} B_{2(g)}$ having degree of dissociation $ x $ (small compared to unity). The correct expression for $ x $ in terms of $ K_p $ and $ p...
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7Chemical Kinetics And Nuclear Chemistry
The reaction $A_2 + B_2 \rightarrow 2AB$ follows the mechanism:$A_2 \overset{k_1}{\underset{k_{-1}}{\rightleftharpoons}} A + A$ (fast)$A + B_2 \xrightarrow{k_2} AB + B$ (slow)$A + B \rightarrow AB$ (fast)The overall order of the reaction is...
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8Compounds Containing Nitrogen
In the following substitution reaction :
Product 'P' formed is :
Product 'P' formed is :
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9Compounds Containing Nitrogen
The steam volatile compounds among the following are :
$\text { Choose the correct answer from the options given below : }$
$\text { Choose the correct answer from the options given below : }$
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10Compounds Containing Nitrogen
Given below are some nitrogen containing compounds :Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume _______ mg of HCl.(Given molar mass in g mol−1 C : 12, H : 1, O : 16, Cl : 35.5)
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11Coordination Compounds
The correct increasing order of stability of the complexes based on $\Delta_0$ value is :
I. $[\text{Mn}(\text{CN})_6]^{3-}$
II. $[\text{Co}(\text{CN})_6]^{4-}$
III. $[\text{Fe}(\text{CN})_6]^{4-}$
IV. $[\text{Fe}(\text{CN})_6]^{3-}$
I. $[\text{Mn}(\text{CN})_6]^{3-}$
II. $[\text{Co}(\text{CN})_6]^{4-}$
III. $[\text{Fe}(\text{CN})_6]^{4-}$
IV. $[\text{Fe}(\text{CN})_6]^{3-}$
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12Coordination Compounds
Match List - I with List - II.
List - I (Complex)
List - II (Hybridisation & Magnetic characters)
(A) [MnBr4]2-
(I) d2sp3 & diamagnetic
(B) [FeF6]3-
(II) sp3d2 & paramagnetic
(C) [Co(C2O4)3]...
List - I (Complex)
List - II (Hybridisation & Magnetic characters)
(A) [MnBr4]2-
(I) d2sp3 & diamagnetic
(B) [FeF6]3-
(II) sp3d2 & paramagnetic
(C) [Co(C2O4)3]...
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13D And F Block Elements
The correct option with order of melting points of the pairs (Mn, Fe), (Tc, Ru) and (Re, Os) is :
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14D And F Block Elements
The molar mass of the water insoluble product formed from the fusion of chromite ore (FeCr₂O₄) with Na₂CO₃ in presence of O₂ is ___________ g mol⁻¹.
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15Electrochemistry
For a Mg | Mg2+ (aq) || Ag+ (aq) | Ag the correct Nernst Equation is :
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16Electrochemistry
The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed?
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17Electrochemistry
The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.
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18Hydrocarbons
The sum of sigma (σ) and pi (π) bonds in Hex-1,3-dien-5-yne is ________.
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19Periodic Table And Periodicity
An element ‘E’ has the ionisation enthalpy value of 374 kJ mol⁻¹. ‘E’ reacts with elements A, B, C and D with electron gain enthalpy values of −328, −349, −325 and −295 kJ mol⁻¹, respectively. The correct order of the products EA, EB, EC an...
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20Periodic Table And Periodicity
Given below are two statements :Statement (I) : The radii of isoelectronic species increases in the order.
Mg2+ < Na+ < F$-$ < O2-Statement (II) : The magnitude of electron gain enthalpy of halogen decreases in the order.
Cl > F > Br > IIn ...
Mg2+ < Na+ < F$-$ < O2-Statement (II) : The magnitude of electron gain enthalpy of halogen decreases in the order.
Cl > F > Br > IIn ...
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21Solutions
1.24 g of AX2 (molar mass 124 g mol−1) is dissolved in 1 kg of water to form a solution with boiling point of 100.015°C, while 25.4 g of AY2 (molar mass 250 g mol−1) in 2 kg of water constitutes a solution with a boiling point of 100.0260°C...
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22Solutions
If A2B is 30% ionised in an aqueous solution, then the value of van't Hoff factor (i) is _______ × 10−1.
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23Some Basic Concepts Of Chemistry
Choose the correct statements.(A) Weight of a substance is the amount of matter present in it.(B) Mass is the force exerted by gravity on an object.(C) Volume is the amount of space occupied by a substance.(D) Temperatures below 0°C are pos...
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24Structure Of Atom
If $a$0 is denoted as the Bohr radius of hydrogen atom, then what is the de-Broglie wavelength (λ) of the electron present in the second orbit of hydrogen atom? [n : any integer]
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25Thermodynamics
500 J of energy is transferred as heat to 0.5 mol of Argon gas at 298 K and 1.00 atm. The final temperature and the change in internal energy respectively are: Given: R = 8.3 J K-1 mol-1
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263d Geometry
Let $\mathrm{L}_1: \frac{x-1}{1}=\frac{y-2}{-1}=\frac{z-1}{2}$ and $\mathrm{L}_2: \frac{x+1}{-1}=\frac{y-2}{2}=\frac{z}{1}$ be two lines.
Let $L_3$ be a line passing through the point $(\alpha, \beta, \gamma)$ and be perpendicular to both $...
Let $L_3$ be a line passing through the point $(\alpha, \beta, \gamma)$ and be perpendicular to both $...
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27Area Under The Curves
Let the area of the region $ (x, y) : 2y \leq x^2 + 3,\ y + |x| \leq 3, \ y \geq |x - 1| $ be $ A $. Then $ 6A $ is equal to :
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28Binomial Theorem
The least value of n for which the number of integral terms in the Binomial expansion of $(\sqrt[3]{7}+\sqrt[12]{11})^n$ is 183, is :
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29Circle
Let the line x+y=1 meet the circle $x^2+y^2=4$ at the points A and B. If the line perpendicular to AB and passing through the mid-point of the chord AB intersects the circle at C and D, then the area of the quadrilateral ABCD is equal to :
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30Complex Numbers
Let $ |z_1 − 8−2i| \leq 1 $ and $ |z_2−2+6i| \leq 2 $, $ z_1, z_2 \in \mathbb{C} $. Then the minimum value of $ |z_1 − z_2| $ is :
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31Definite Integration
The integral $80 \int\limits_0^{\frac{\pi}{4}}\left(\frac{\sin \theta+\cos \theta}{9+16 \sin 2 \theta}\right) d \theta$ is equal to :
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32Definite Integration
Let $f:(0, \infty) \rightarrow \mathbf{R}$ be a twice differentiable function. If for some $a\ne 0, \int\limits_0^1 f(\lambda x) \mathrm{d} \mathrm{\lambda}=a f(x), f(1)=1$ and $f(16)=\frac{1}{8}$, then $16-f^{\prime}\left(\frac{1}{16}\righ...
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33Differential Equations
Let y = y(x) be the solution of the differential equation :
$\cos x\left(\log _e(\cos x)\right)^2 d y+\left(\sin x-3 y \sin x \log _e(\cos x)\right) d x=0$, x ∈ (0, $\frac{\pi}{2}$ ). If $ y(\frac{\pi}{4}) $ = $-\frac{1}{\log_{e}2}$, then $...
$\cos x\left(\log _e(\cos x)\right)^2 d y+\left(\sin x-3 y \sin x \log _e(\cos x)\right) d x=0$, x ∈ (0, $\frac{\pi}{2}$ ). If $ y(\frac{\pi}{4}) $ = $-\frac{1}{\log_{e}2}$, then $...
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34Ellipse
Let the ellipse $E_1: \frac{x^2}{a^2} + \frac{y^2}{b^2} = 1$, $a > b$ and $E_2: \frac{x^2}{A^2} + \frac{y^2}{B^2} = 1$, $A < B$ have same eccentricity $\frac{1}{\sqrt{3}}$. Let the product of their lengths of latus rectums be $\frac{32}{\sq...
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35Inverse Trigonometric Functions
Let S = $ \left\{ x : \cos^{-1} x = \pi + \sin^{-1} x + \sin^{-1} [2x + 1] \right\} $. Then $ \sum\limits_{x \in S} (2x - 1)^2 $ is equal to _______.
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36Limits Continuity And Differentiability
The value of $\lim \limits_{n \rightarrow \infty}\left(\sum\limits_{k=1}^n \frac{k^3+6 k^2+11 k+5}{(k+3)!}\right)$ is :
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37Limits Continuity And Differentiability
Let [t] be the greatest integer less than or equal to t. Then the least value of p ∈ N for which
$ \lim\limits_{x \to 0^+} \left( x (\left[ \frac{1}{x} \right] + \left[ \frac{2}{x} \right] + \ldots + \left[ \frac{p}{x} \right] \right) - x^2...
$ \lim\limits_{x \to 0^+} \left( x (\left[ \frac{1}{x} \right] + \left[ \frac{2}{x} \right] + \ldots + \left[ \frac{p}{x} \right] \right) - x^2...
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38Matrices And Determinants
Let $ A = \begin{bmatrix} a_{ij} \end{bmatrix} = \begin{bmatrix} \log_5 128 & \log_4 5 \\ \log_5 8 & \log_4 25 \end{bmatrix} $. If $ A_{ij} $ is the cofactor of $ a_{ij} $, $ C_{ij} = \sum\limits_{k=1}^{2} a_{ik} A_{jk} , 1 \leq i, j \leq 2...
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39Matrices And Determinants
Let M and m respectively be the maximum and the minimum values of
$f(x)=\left|\begin{array}{ccc}1+\sin ^2 x & \cos ^2 x & 4 \sin 4 x \\ \sin ^2 x & 1+\cos ^2 x & 4 \sin 4 x \\ \sin ^2 x & \cos ^2 x & 1+4 \sin 4 x\end{array}\right|, x \in R$...
$f(x)=\left|\begin{array}{ccc}1+\sin ^2 x & \cos ^2 x & 4 \sin 4 x \\ \sin ^2 x & 1+\cos ^2 x & 4 \sin 4 x \\ \sin ^2 x & \cos ^2 x & 1+4 \sin 4 x\end{array}\right|, x \in R$...
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40Matrices And Determinants
Let $S=\left\{m \in \mathbf{Z}: A^{m^2}+A^m=3 I-A^{-6}\right\}$, where $A=\left[\begin{array}{cc}2 & -1 \\ 1 & 0\end{array}\right]$. Then $n(S)$ is equal to __________.
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41Parabola
Two parabolas have the same focus (4, 3) and their directrices are the x-axis and the y-axis, respectively. If these parabolas intersect at the points A and B, then (AB)2 is equal to :
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42Permutations And Combinations
Let $ P $ be the set of seven digit numbers with sum of their digits equal to 11. If the numbers in $ P $ are formed by using the digits 1, 2 and 3 only, then the number of elements in the set $ P $ is :
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43Permutations And Combinations
The number of 6-letter words, with or without meaning, that can be formed using the letters of the word MATHS such that any letter that appears in the word must appear at least twice, is _________.
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44Quadratic Equation And Inequalities
The number of solutions of the equation $ \left( \frac{9}{x} - \frac{9}{\sqrt{x}} + 2 \right) \left( \frac{2}{x} - \frac{7}{\sqrt{x}} + 3 \right) = 0 $ is :
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45Sequences And Series
Consider an A. P. of positive integers, whose sum of the first three terms is 54 and the sum of the first twenty terms lies between 1600 and 1800. Then its 11th term is :
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46Sets And Relations
Define a relation R on the interval $ \left[0, \frac{\pi}{2}\right) $ by $ x $ R $ y $ if and only if $ \sec^2x - \tan^2y = 1 $. Then R is :
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47Statistics
Let $x_1, x_2, ..., x_{10}$ be ten observations such that $\sum\limits_{i=1}^{10} (x_i - 2) = 30$, $\sum\limits_{i=1}^{10} (x_i - \beta)^2 = 98$, $\beta > 2$, and their variance is $\frac{4}{5}$. If $\mu$ and $\sigma^2$ are respectively the...
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48Straight Lines And Pair Of Straight Lines
Let ΔABC be a triangle formed by the lines 7x – 6y + 3 = 0, x + 2y – 31 = 0 and 9x – 2y – 19 = 0. Let the point (h, k) be the image of the centroid of ΔABC in the line 3x + 6y – 53 = 0. Then h2 + k2 + hk is equal to :
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49Vector Algebra
Let $\vec{a}=\hat{i}+2 \hat{j}+\hat{k}$ and $\vec{b}=2 \hat{i}+7 \hat{j}+3 \hat{k}$. Let $\mathrm{L}_1 : \overrightarrow{\mathrm{r}}=(-\hat{i}+2 \hat{j}+\hat{k})+\lambda \vec{a}, \mathrm{\lambda} \in \mathbf{R}$ and $\mathrm{L}_2: \overrigh...
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50Vector Algebra
Let $ \vec{a} = 2\hat{i} - \hat{j} + 3\hat{k}, \ \vec{b} = 3\hat{i} - 5\hat{j} + \hat{k} $ and $ \vec{c} $ be a vector such that $ \vec{a} \times \vec{c} = \vec{a} \times \vec{b} = \vec{c} \times \vec{b} $ and $ (\vec{a} + \vec{c}) \cdot (\...
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