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Structure of Atom

JEE Main / Chemistry / Physical Chemistry / 220 questions

ChemistryPhysical Chemistry220 PYQs

Practice 220 JEE Main Chemistry questions from Structure of Atom. Use the year-wise and type-wise breakdown to prioritize recent PYQs, then continue into the question list below.

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2002-2026
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Structure of Atom Questions

Showing 50 of 220 questions on this page.

1Structure Of Atom
A hypothetical electromagnetic wave is show below.

The frequency of the wave is \(\mathrm{x} \times 10^{19} \mathrm{~Hz}\).
\(\mathrm{x}=\) _________ (nearest integer)
INTEGER+4 / -12024
2Structure Of Atom
Wavenumber for a radiation having 5800 \(\mathop A\limits^o\) wavelength is \(x \times 10 \mathrm{~cm}^{-1}\) The value of \(x\) is ________. (Integer answer)
INTEGER+4 / -12024
3Structure Of Atom
Frequency of the de-Broglie wave of electron in Bohr's first orbit of hydrogen atom is _________ \(\times 10^{13} \mathrm{~Hz}\) (nearest integer).
[Given : \(\mathrm{R}_{\mathrm{H}}\) (Rydberg constant) $$=2.18 \times 10^{-18} \mathrm{~J},...
INTEGER+4 / -12024
4Structure Of Atom
For hydrogen atom, energy of an electron in first excited state is \(-3.4 \mathrm{~eV}, \mathrm{K} . \mathrm{E}\). of the same electron of hydrogen atom is \(x \mathrm{~eV}\). Value of \(x\) is _________ \(\times 10^{-1} \mathrm{~eV}\). (Ne...
INTEGER+4 / -12024
5Structure Of Atom
The value of Rydberg constant \((R_H)\) is \(2.18 \times 10^{-18} \mathrm{~J}\). The velocity of electron having mass \(9.1 \times 10^{-31} \mathrm{~kg}\) in Bohr's first orbit of hydrogen atom = ________ \(\times 10^5 \mathrm{~ms}^{-1}\) (...
INTEGER+4 / -12024
6Structure Of Atom
The incorrect postulates of the Dalton's atomic theory are :
(A) Atoms of different elements differ in mass.
(B) Matter consists of divisible atoms.
(C) Compounds are formed when atoms of different element combine in a fixed ratio.
(D) All ...
MCQ+4 / -12024
7Structure Of Atom
In an atom, total number of electrons having quantum numbers \(\mathrm{n}=4,\left|\mathrm{~m}_l\right|=1\) and \(\mathrm{m}_{\mathrm{s}}=-\frac{1}{2}\) is _________.
INTEGER+4 / -12024
8Structure Of Atom
The de-Broglie's wavelength of an electron in the \(4^{\text {th }}\) orbit is ________ \(\pi \mathrm{a}_0\). (\(\mathrm{a}_0=\) Bohr's radius)
INTEGER+4 / -12024
9Structure Of Atom
The maximum number of orbitals which can be identified with \(\mathrm{n}=4\) and \(m_l=0\) is _________.
INTEGER+4 / -12024
10Structure Of Atom
Choose the Incorrect Statement about Dalton's Atomic Theory
MCQ+4 / -12024
11Structure Of Atom
The ionization energy of sodium in \(\mathrm{~kJ} \mathrm{~mol}^{-1}\), if electromagnetic radiation of wavelength \(242 \mathrm{~nm}\) is just sufficient to ionize sodium atom is _______.
INTEGER+4 / -12024
12Structure Of Atom
The four quantum numbers for the electron in the outer most orbital of potassium (atomic no. 19) are
MCQ+4 / -12024
13Structure Of Atom
Given below are two statements :
Statement (I) : The orbitals having same energy are called as degenerate orbitals.
Statement (II) : In hydrogen atom, 3p and 3d orbitals are not degenerate orbitals.
In the light of the above statements, cho...
MCQ+4 / -12024
14Structure Of Atom
Number of spectral lines obtained in \(\mathrm{He}^{+}\) spectra, when an electron makes transition from fifth excited state to first excited state will be
INTEGER+4 / -12024
15Structure Of Atom
The correct set of four quantum numbers for the valence electron of rubidium atom \((\mathrm{Z}=37)\) is :
MCQ+4 / -12024
16Structure Of Atom
Match List I with List II

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MCQ+4 / -12024
17Structure Of Atom
The number of electrons present in all the completely filled subshells having \(\mathrm{n}=4\) and \(\mathrm{s}=+\frac{1}{2}\) is _______.
(Where \(\mathrm{n}=\) principal quantum number and \(\mathrm{s}=\) spin quantum number)
INTEGER+4 / -12024
18Structure Of Atom
According to the wave-particle duality of matter by de-Broglie, which of the following graph plot presents most appropriate relationship between wavelength of electron $(\lambda)$ and momentum of electron $(p)$?
MCQ+4 / -12024
19Structure Of Atom
In case of isoelectronic species the size of $\mathrm{F}^{-}, \mathrm{Ne}$ and $\mathrm{Na}^{+}$is affected by :
MCQ+4 / -12024
20Structure Of Atom
The number of radial node/s for $3 p$ orbital is :
MCQ+4 / -12024
21Structure Of Atom
The number of following statement/s which is/are incorrect is ___________
(A) Line emission spectra are used to study the electronic structure
(B) The emission spectra of atoms in the gas phase show a continuous spread of wavelength from re...
INTEGER+4 / -12023
22Structure Of Atom
The number of atomic orbitals from the following having 5 radial nodes is ___________.
\(7 \mathrm{s}, 7 \mathrm{p}, 6 \mathrm{s}, 8 \mathrm{p}, 8 \mathrm{d}\)
INTEGER+4 / -12023
23Structure Of Atom
Henry Moseley studied characteristic X-ray spectra of elements. The graph which represents his observation correctly is
Given \(v=\) frequency of \(\mathrm{X}\)-ray emitted
Z = atomic number
MCQ+4 / -12023
24Structure Of Atom
The wavelength of an electron of kinetic energy \(4.50\times10^{-29}\) J is _________ \(\times 10^{-5}\) m. (Nearest integer)
Given : mass of electron is \(9\times10^{-31}\) kg, h \(=6.6\times10^{-34}\) J s
INTEGER+4 / -12023
25Structure Of Atom
If the radius of the first orbit of hydrogen atom is \(\alpha_{0}\), then de Broglie's wavelength of electron in \(3^{\text {rd }}\) orbit is :
MCQ+4 / -12023
26Structure Of Atom
Which transition in the hydrogen spectrum would have the same wavelength as the Balmer type transition from \(\mathrm{n=4}\) to \(\mathrm{n}=2\) of \(\mathrm{He}^{+}\) spectrum
MCQ+4 / -12023
27Structure Of Atom
Arrange the following orbitals in decreasing order of energy.
A. $\mathrm{n}=3, \mathrm{l}=0, \mathrm{~m}=0$
B. $\mathrm{n}=4, \mathrm{l}=0, \mathrm{~m}=0$
C. $\mathrm{n}=3, \mathrm{l}=1, \mathrm{~m}=0$
D. $\mathrm{n}=3, \mathrm{l}=2, \math...
MCQ+4 / -12023
28Structure Of Atom
The energy of one mole of photons of radiation of frequency \(2 \times 10^{12} \mathrm{~Hz}\) in \(\mathrm{J} ~\mathrm{mol}^{-1}\) is ___________. (Nearest integer)
[Given : \(\mathrm{h}=6.626 \times 10^{-34} ~\mathrm{Js}\)
$$\mathrm{N}_{\m...
INTEGER+4 / -12023
29Structure Of Atom
The wave function $(\Psi)$ of $2 \mathrm{~s}$ is given by
\(\Psi_{2 \mathrm{~s}}=\frac{1}{2 \sqrt{2 \pi}}\left(\frac{1}{a_0}\right)^{1 / 2}\left(2-\frac{r}{a_0}\right) e^{-r / 2 a_0}\)
At $r=r_0$, radial node is formed. Thus, $r_0$ in ter...
MCQ+4 / -12023
30Structure Of Atom
Maximum number of electrons that can be accommodated in shell with $n=4$ are:
MCQ+4 / -12023
31Structure Of Atom
The shortest wavelength of hydrogen atom in Lyman series is \(\lambda\). The longest wavelength is Balmer series of He\(^+\) is
MCQ+4 / -12023
32Structure Of Atom
Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6 \(\mathrm{\mathop A\limits^o }\). The radius of the third Bohr orbit of He\(^+\) is __________ picometer. (Nearest Integer)
INTEGER+4 / -12023
33Structure Of Atom
The radius of the \(\mathrm{2^{nd}}\) orbit of \(\mathrm{Li^{2+}}\) is \(x\). The expected radius of the \(\mathrm{3^{rd}}\) orbit of \(\mathrm{Be^{3+}}\) is
MCQ+4 / -12023
34Structure Of Atom
The number of given orbitals which have electron density along the axis is _________
\(\mathrm{p_x,p_y,p_z,d_{xy},d_{yz},d_{xz},d_{z^2},d_{x^2-y^2}}\)
INTEGER+4 / -12023
35Structure Of Atom
If wavelength of the first line of the Paschen series of hydrogen atom is 720 nm, then the wavelength of the second line of this series is _________ nm. (Nearest integer)
INTEGER+4 / -12023
36Structure Of Atom
It is observed that characteristic X-ray spectra of elements show regularity. When frequency to the power "n" i.e. \({v^n}\) of X-rays emitted is plotted against atomic number "Z", following graph is obtained.

The value of 'n' is :
MCQ+4 / -12023
37Structure Of Atom
The magnetic moment of a transition metal compound has been calculated to be 3.87 B.M. The metal ion is
MCQ+4 / -12023
38Structure Of Atom
The number of s-electrons present in an ion with 55 protons in its unipositive state is
MCQ+4 / -12023
39Structure Of Atom
Electrons in a cathode ray tube have been emitted with a velocity of 1000 m s\(^{-1}\). The number of following statements which is/are \(\underline {\mathrm{true}}\) about the emitted radiation is ____________.
Given : $$\mathrm{h=6\times...
INTEGER+4 / -12023
40Structure Of Atom
Which one of the following sets of ions represents a collection of isoelectronic species?
(Given : Atomic Number : \(\mathrm{F:9,Cl:17,Na=11,Mg=12,Al=13,K=19,Ca=20,Sc=21}\))
MCQ+4 / -12023
41Structure Of Atom
The total number of isoelectronic species from the given set is ___________.
$\mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Al}, \mathrm{Mg}^{2+}, \mathrm{Na}^{+}, \mathrm{O}^{+}, \mathrm{Mg}, \mathrm{Al}^{3+}, \mathrm{F}$
INTEGER+4 / -12023
42Structure Of Atom
Given below are two statements:

Statement I : According to Bohr's model of hydrogen atom, the angular momentum of an electron in a given stationary state is quantised.

Statement II : The concept of electron in Bohr's orbit, violates the H...
MCQ+4 / -12023
43Structure Of Atom
The energy of an electron in the first Bohr orbit of hydrogen atom is \(-2.18 \times 10^{-18} \mathrm{~J}\). Its energy in the third Bohr orbit is ____________.
MCQ+4 / -12023
44Structure Of Atom
The orbital angular momentum of an electron in \(3 \mathrm{~s}\) orbital is \(\frac{x h}{2 \pi}\). The value of \(x\) is ____________ (nearest integer)
INTEGER+4 / -12023
45Structure Of Atom
Values of work function (W\(_0\)) for a few metals are given below

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overflow:hid...
INTEGER+4 / -12023
46Structure Of Atom
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A : In the photoelectric effect, the electrons are ejected from the metal surface as soon as the beam of light of frequency gr...
MCQ+4 / -12023
47Structure Of Atom
The number of correct statements from the following is ___________.
A. For \(1 \mathrm{s}\) orbital, the probability density is maximum at the nucleus
B. For \(2 \mathrm{s}\) orbital, the probability density first increases to maximum and t...
INTEGER+4 / -12023
48Structure Of Atom
The number of incorrect statement/s about the black body from the following is __________
(A) Emit or absorb energy in the form of electromagnetic radiation.
(B) Frequency distribution of the emitted radiation depends on temperature.
(C) At...
INTEGER+4 / -12023
49Structure Of Atom

The electron in the \(\mathrm{n}^{\text {th }}\) orbit of \(\mathrm{Li}^{2+}\) is excited to \((\mathrm{n}+1)\) orbit using the radiation of energy \(1.47 \times 10^{-17} \mathrm{~J}\) (as shown in the diagram). The value of \(\mathrm{n}\)...
INTEGER+4 / -12023
50Structure Of Atom
The number of radial nodes and total number of nodes in 4p orbital respectively are :
MCQ+4 / -12022

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