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JEE Main 2024 (Online) 4th April Morning Shift

JEE Main / 90 questions

2026Thu, Apr 4, 2024 3:30 AM90 PYQs
1Aldehydes Ketones And Carboxylic Acids
Given below are two statements :
Statements I : Acidity of \(\alpha\)-hydrogens of aldehydes and ketones is responsible for Aldol reaction.
Statement II : Reaction between benzaldehyde and ethanal will NOT give Cross - Aldol product.
In the...
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2Aldehydes Ketones And Carboxylic Acids
Identify the product in the following reaction:
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3Basics Of Organic Chemistry
What will be the decreasing order of basic strength of the following conjugate bases? \({ }^{-} \mathrm{OH}, \mathrm{R} \overline{\mathrm{O}}, \mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}, \mathrm{Cl}\)

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4Basics Of Organic Chemistry
Which among the following is incorrect statement?
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5Basics Of Organic Chemistry
The number of different chain isomers for C\(_7\)H\(_{16}\) is __________.
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6Basics Of Organic Chemistry
Match List I with List II :

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7Biomolecules
Which of the following is the correct structure of L-Glucose?
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8Chemical Bonding And Molecular Structure
Number of molecules/ions from the following in which the central atom is involved in \(\mathrm{sp}^3\) hybridization is ________.
\(\mathrm{NO}_3^{-}, \mathrm{BCl}_3, \mathrm{ClO}_2^{-}, \mathrm{ClO}_3^{-}\)
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9Chemical Bonding And Molecular Structure
Which one of the following molecules has maximum dipole moment?
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10Chemical Bonding And Molecular Structure
Number of molecules/species from the following having one unpaired electron is ________.
\(\mathrm{O}_2, \mathrm{O}_2^{-1}, \mathrm{NO}, \mathrm{CN}^{-1}, \mathrm{O}_2^{2-}\)
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11Chemical Kinetics And Nuclear Chemistry
Consider the following transformation involving first order elementary reaction in each step at constant temperature as shown below.

Some details of the above reactions are listed below.

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....
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12Compounds Containing Nitrogen
Which of the following nitrogen containing compound does not give Lassaigne's test ?
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13Compounds Containing Nitrogen
The number of the correct reaction(s) among the following is _______.
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14Coordination Compounds
Number of complexes from the following with even number of unpaired "\(\mathrm{d}\)" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]...
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15Coordination Compounds
The correct sequence of ligands in the order of decreasing field strength is :
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16D And F Block Elements
The element which shows only one oxidation state other than its elemental form is :
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17D And F Block Elements
Consider the following reaction
\(\mathrm{MnO}_2+\mathrm{KOH}+\mathrm{O}_2 \rightarrow \mathrm{A}+\mathrm{H}_2 \mathrm{O} \text {. }\)
Product '\(\mathrm{A}\)' in neutral or acidic medium disproportionate to give products '\(\mathrm{B}\)' a...
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18Electrochemistry
One of the commonly used electrode is calomel electrode. Under which of the following categories, calomel electrode comes?
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19Electrochemistry
What pressure (bar) of \(\mathrm{H}_2\) would be required to make emf of hydrogen electrode zero in pure water at \(25^{\circ} \mathrm{C}\) ?
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20Haloalkanes And Haloarenes

Identify B and C and how are A and C related?
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21Haloalkanes And Haloarenes
Identify the correct set of reagents or reaction conditions '\(X\)' and '\(Y\)' in the following set of transformation.
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22Periodic Table And Periodicity
The correct order of first ionization enthalpy values of the following elements is :
(A) O
(B) N
(C) Be
(D) F
(E) B
Choose the correct answer from the options given below :
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23Periodic Table And Periodicity
Number of elements from the following that CANNOT form compounds with valencies which match with their respective group valencies is ________. B, C, N, S, O, F, P, Al, Si
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24Redox Reactions
Only \(2 \mathrm{~mL}\) of \(\mathrm{KMnO}_4\) solution of unknown molarity is required to reach the end point of a titration of \(20 \mathrm{~mL}\) of oxalic acid \((2 \mathrm{M})\) in acidic medium. The molarity of \(\mathrm{KMnO}_4\) sol...
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25Salt Analysis
In the precipitation of the iron group (III) in qualitative analysis, ammonium chloride is added before adding ammonium hydroxide to :
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26Solutions
\(2.5 \mathrm{~g}\) of a non-volatile, non-electrolyte is dissolved in \(100 \mathrm{~g}\) of water at \(25^{\circ} \mathrm{C}\). The solution showed a boiling point elevation by \(2^{\circ} \mathrm{C}\). Assuming the solute concentration i...
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27Some Basic Concepts Of Chemistry
The Molarity (M) of an aqueous solution containing \(5.85 \mathrm{~g}\) of \(\mathrm{NaCl}\) in \(500 \mathrm{~mL}\) water is : (Given : Molar Mass \(\mathrm{Na}: 23\) and \(\mathrm{Cl}: 35.5 \mathrm{~gmol}^{-1}\))
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28Some Basic Concepts Of Chemistry
\(\mathrm{Xg}\) of ethylamine is subjected to reaction with \(\mathrm{NaNO}_2 / \mathrm{HCl}\) followed by water; evolved dinitrogen gas which occupied \(2.24 \mathrm{~L}\) volume at STP. X is _________ \(\times 10^{-1} \mathrm{~g}\).
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29Structure Of Atom
The de-Broglie's wavelength of an electron in the \(4^{\text {th }}\) orbit is ________ \(\pi \mathrm{a}_0\). (\(\mathrm{a}_0=\) Bohr's radius)
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30Thermodynamics
The enthalpy of formation of ethane \((\mathrm{C}_2 \mathrm{H}_6)\) from ethylene by addition of hydrogen where the bond-energies of \(\mathrm{C}-\mathrm{H}, \mathrm{C}-\mathrm{C}, \mathrm{C}=\mathrm{C}, \mathrm{H}-\mathrm{H}\) are $$414 \m...
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313d Geometry
Let the point, on the line passing through the points \(P(1,-2,3)\) and \(Q(5,-4,7)\), farther from the origin and at a distance of 9 units from the point \(P\), be \((\alpha, \beta, \gamma)\). Then \(\alpha^2+\beta^2+\gamma^2\) is equal to...
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32Application Of Derivatives
Let the sum of the maximum and the minimum values of the function \(f(x)=\frac{2 x^2-3 x+8}{2 x^2+3 x+8}\) be \(\frac{m}{n}\), where \(\operatorname{gcd}(\mathrm{m}, \mathrm{n})=1\). Then \(\mathrm{m}+\mathrm{n}\) is equal to :
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33Area Under The Curves
One of the points of intersection of the curves \(y=1+3 x-2 x^2\) and \(y=\frac{1}{x}\) is \(\left(\frac{1}{2}, 2\right)\). Let the area of the region enclosed by these curves be $$\frac{1}{24}(l \sqrt{5}+\mathrm{m})-\mathrm{n} \log _{\math...
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34Binomial Theorem
The sum of all rational terms in the expansion of \(\left(2^{\frac{1}{5}}+5^{\frac{1}{3}}\right)^{15}\) is equal to :
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35Binomial Theorem
Let $$a=1+\frac{{ }^2 \mathrm{C}_2}{3 !}+\frac{{ }^3 \mathrm{C}_2}{4 !}+\frac{{ }^4 \mathrm{C}_2}{5 !}+...., \mathrm{b}=1+\frac{{ }^1 \mathrm{C}_0+{ }^1 \mathrm{C}_1}{1 !}+\frac{{ }^2 \mathrm{C}_0+{ }^2 \mathrm{C}_1+{ }^2 \mathrm{C}_2}{2 !}...
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36Circle
A square is inscribed in the circle \(x^2+y^2-10 x-6 y+30=0\). One side of this square is parallel to \(y=x+3\). If \(\left(x_i, y_i\right)\) are the vertices of the square, then \(\Sigma\left(x_i^2+y_i^2\right)\) is equal to:
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37Complex Numbers
Let \(\alpha\) and \(\beta\) be the sum and the product of all the non-zero solutions of the equation \((\bar{z})^2+|z|=0, z \in C\). Then \(4(\alpha^2+\beta^2)\) is equal to :
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38Definite Integration
$$\text { Let } f(x)=\left\{\begin{array}{lr} -2, & -2 \leq x \leq 0 \\ x-2, & 0< x \leq 2 \end{array} \text { and } \mathrm{h}(x)=f(|x|)+|f(x)| \text {. Then } \int_\limits{-2}^2 \mathrm{~h}(x) \mathrm{d} x\right. \text { is equal to: }$$
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39Definite Integration
If the shortest distance between the lines \(\frac{x+2}{2}=\frac{y+3}{3}=\frac{z-5}{4}\) and \(\frac{x-3}{1}=\frac{y-2}{-3}=\frac{z+4}{2}\) is \(\frac{38}{3 \sqrt{5}} \mathrm{k}\), and $$\int_\limits 0^{\mathrm{k}}\left[x^2\right] \mathrm{d...
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40Definite Integration
If \(\int_0^{\frac{\pi}{4}} \frac{\sin ^2 x}{1+\sin x \cos x} \mathrm{~d} x=\frac{1}{\mathrm{a}} \log _{\mathrm{e}}\left(\frac{\mathrm{a}}{3}\right)+\frac{\pi}{\mathrm{b} \sqrt{3}}\), where \(\mathrm{a}, \mathrm{b} \in \mathrm{N}\), then $$...
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41Differential Equations
If the solution \(y=y(x)\) of the differential equation \((x^4+2 x^3+3 x^2+2 x+2) \mathrm{d} y-(2 x^2+2 x+3) \mathrm{d} x=0\) satisfies \(y(-1)=-\frac{\pi}{4}\), then \(y(0)\) is equal to :
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42Differential Equations
Let the solution \(y=y(x)\) of the differential equation \(\frac{\mathrm{d} y}{\mathrm{~d} x}-y=1+4 \sin x\) satisfy \(y(\pi)=1\). Then \(y\left(\frac{\pi}{2}\right)+10\) is equal to __________.
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43Differentiation
Let \(f(x)=x^5+2 \mathrm{e}^{x / 4}\) for all \(x \in \mathbf{R}\). Consider a function \(g(x)\) such that \((g \circ f)(x)=x\) for all \(x \in \mathbf{R}\). Then the value of \(8 g^{\prime}(2)\) is :
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44Inverse Trigonometric Functions
If the domain of the function \(\sin ^{-1}\left(\frac{3 x-22}{2 x-19}\right)+\log _{\mathrm{e}}\left(\frac{3 x^2-8 x+5}{x^2-3 x-10}\right)\) is \((\alpha, \beta]\), then \(3 \alpha+10 \beta\) is equal to:
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45Limits Continuity And Differentiability
Let \(f: \mathbf{R} \rightarrow \mathbf{R}\) be a function given by
$$f(x)= \begin{cases}\frac{1-\cos 2 x}{x^2}, & x < 0 \\ \alpha, & x=0, \\ \frac{\beta \sqrt{1-\cos x}}{x}, & x>0\end{cases}$$
where \(\alpha, \beta \in \mathbf{R}\). If $$f...
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46Limits Continuity And Differentiability
If \(\lim _\limits{x \rightarrow 1} \frac{(5 x+1)^{1 / 3}-(x+5)^{1 / 3}}{(2 x+3)^{1 / 2}-(x+4)^{1 / 2}}=\frac{\mathrm{m} \sqrt{5}}{\mathrm{n}(2 \mathrm{n})^{2 / 3}}\), where \(\operatorname{gcd}(\mathrm{m}, \mathrm{n})=1\), then $$8 \mathrm...
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47Matrices And Determinants
Let \(\alpha \in(0, \infty)\) and $$A=\left[\begin{array}{lll}1 & 2 & \alpha \\ 1 & 0 & 1 \\ 0 & 1 & 2\end{array}\right]$$. If $$\operatorname{det}\left(\operatorname{adj}\left(2 A-A^T\right) \cdot \operatorname{adj}\left(A-2 A^T\right)\rig...
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48Matrices And Determinants
If the system of equations
$$\begin{aligned} & x+(\sqrt{2} \sin \alpha) y+(\sqrt{2} \cos \alpha) z=0 \\ & x+(\cos \alpha) y+(\sin \alpha) z=0 \\ & x+(\sin \alpha) y-(\cos \alpha) z=0 \end{aligned}$$
has a non-trivial solution, then $$\alpha...
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49Matrices And Determinants
Let \(A\) be a square matrix of order 2 such that \(|A|=2\) and the sum of its diagonal elements is \(-\)3 . If the points \((x, y)\) satisfying \(\mathrm{A}^2+x \mathrm{~A}+y \mathrm{I}=\mathrm{O}\) lie on a hyperbola, whose transverse axi...
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50Matrices And Determinants
Let \(A\) be a \(3 \times 3\) matrix of non-negative real elements such that $$A\left[\begin{array}{l}1 \\ 1 \\ 1\end{array}\right]=3\left[\begin{array}{l}1 \\ 1 \\ 1\end{array}\right]$$. Then the maximum value of $$\operatorname{det}(\math...
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