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Chemical Kinetics And Nuclear Chemistry

JEE Main 2024 (Online) 4th April Morning Shift

INTEGER+4 / -12024

Consider the following transformation involving first order elementary reaction in each step at constant temperature as shown below.


JEE Main 2024 (Online) 4th April Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 61 English


Some details of the above reactions are listed below.



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Step Rate constant (sec\(^{-1}\)) Activation energy (kJ mol\(^{-1}\))
1 \(\mathrm{k_1}\) 300
2 \(\mathrm{k_2}\) 200
3 \(\mathrm{k_3}\) \(\mathrm{Ea_3}\)


If the overall rate constant of the above transformation (k) is given as \(\mathrm{k=\frac{k_1 k_2}{k_3}}\) and the overall activation energy \((\mathrm{E}_{\mathrm{a}})\) is \(400 \mathrm{~kJ} \mathrm{~mol} \mathrm{~m}^{-1}\), then the value of \(\mathrm{Ea}_3\) is ________ integer)

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