JEE Advanced 2019 Paper 2 Offline
JEE Advanced / 54 questions
2026Mon, May 27, 2019 2:00 AM54 PYQs
1Aldehydes Ketones And Carboxylic Acids
Choose the correct option(s) for the following reaction sequenceConsider Q, R and S as major products.
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2Aldehydes Ketones And Carboxylic Acids
Which of the following options has correct combination considering List-I and List-II?
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3Aldehydes Ketones And Carboxylic Acids
Which of the following options has correct combination considering List-I and List-II?
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4Basics Of Organic Chemistry
Total number of isomers, considering both structural and stereoisomers of cyclic ethers with the molecular formula C4H8O is .................
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5Chemical Kinetics And Nuclear Chemistry
The decomposition reaction\(2{N_2}{O_5}(g)\buildrel \Delta \over
\longrightarrow 2{N_2}{O_4}(g) + {O_2}(g)\) is started in a closed cylinder under isothermal isochoric condition at an initial pressure of 1 atm. After Y \(\times\) 103 s,...
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6Coordination Compounds
Total number of \(cis\,N - Mn - Cl\) bond angles (that is \(Mn - N\) and \(Mn - Cl\) bonds in cis positions) present in a molecule of \(cis[Mn{(en)_2}C{l_2}]\) complex is ..................(en = NH2CH2CH2NH2)
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7D And F Block Elements
With reference to aqua-regia, choose the correct option(s).
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8Hydrocarbons
Choose the correct option(s) that give(s) an aromatic compound as the major product.
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9Hydrocarbons
Which of the following reactions produce(s) propane as a major product?
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10Hydrocarbons
Total number of hydroxyl groups present in a molecule of the major product P is ..............
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11Isolation Of Elements
The cyanide process of gold extraction involves leaching out gold from its ore with CN\(-\) in the presence of Q in water to form R. Subsequently, R is treated with T to obtain Au and Z. Choose the correct option(s).
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12P Block Elements
Consider the following reactions (unbalanced).\(Zn + Hot\,conc.\,{H_2}S{O_4}\mathrel{\mathop{\kern0pt\longrightarrow}
\limits_{}} G + R + X\)\(Zn + conc.\,NaOH\mathrel{\mathop{\kern0pt\longrightarrow}
\limits_{}} T + Q\)$$G + {H_2}S + N{H_4...
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13Polymers
Choose the correct option(s) from the following.
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14Some Basic Concepts Of Chemistry
The mole fraction of urea in an aqueous urea solution containing 900 g of water is 0.05. If the density of the solution is 1.2 g cm\(-\)3, then molarity of urea solution is ................(Given data : Molar masses of urea and water are 60...
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15Some Basic Concepts Of Chemistry
The amount of water produced (in g) in the oxidation of 1 mole of rhombic sulphur by conc. HNO3 to a compound with the highest oxidation state of sulphur is ..............(Given data : Molar mass of water = 18 g mol\(-\)1)
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16Structure Of Atom
Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the nth orbit of the atom and List-II contains options showing how they depend on n.Which of ...
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17Structure Of Atom
The ground state energy of hydrogen atom is \(-\)13.6 eV. Consider an electronic state \(\psi\) of He+ whose energy, azimuthal quantum number and magnetic quantum number are \(-\)3.4 eV, 2 and 0, respectively.Which of the following stateme...
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18Structure Of Atom
Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the nth orbit of the atom and List-II contains options showing how they depend on n.Which of ...
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193d Geometry
Three lines \({L_1}:r = \lambda \widehat i\), \(\lambda\) \(\in\) R,\({L_2}:r = \widehat k + \mu \widehat j\), \(\mu\) \(\in\) R and \({L_3}:r = \widehat i + \widehat j + v\widehat k\), v \(\in\) R are given.For which point(s) Q on ...
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20Application Of Derivatives
Let f : R \(\to\) R be given by\(f(x) = (x - 1)(x - 2)(x - 5)\). Define\(F(x) = \int\limits_0^x {f(t)dt}\), x > 0Then which of the following options is/are correct?
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21Application Of Derivatives
Let, \(f(x) = {{\sin \pi x} \over {{x^2}}}\), x > 0Let x1 < x2 < x3 < ... < xn < ... be all the points of local maximum of f and y1 < y2 < y3 < ... < yn < ... be all the points of local minimum of f.Then which of the following options is/ar...
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22Definite Integration
The value of the integral \(\int\limits_0^{\pi /2} {{{3\sqrt {\cos \theta } } \over {{{(\sqrt {\cos \theta } + \sqrt {\sin \theta } )}^5}}}} d\theta\) equals ..............
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23Inverse Trigonometric Functions
The value of $${\sec ^{ - 1}}\left( \matrix{
{1 \over 4}\sum\limits_{k = 0}^{10} {\sec \left( {{{7\pi } \over {12}} + {{k\pi } \over 2}} \right)}
\sec \left( {{{7\pi } \over {12}} + {{(k + 1)\pi } \over 2}} \right) \hfill \cr} \right)...
{1 \over 4}\sum\limits_{k = 0}^{10} {\sec \left( {{{7\pi } \over {12}} + {{k\pi } \over 2}} \right)}
\sec \left( {{{7\pi } \over {12}} + {{(k + 1)\pi } \over 2}} \right) \hfill \cr} \right)...
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24Limits Continuity And Differentiability
Let f : R be a function. We say that f has PROPERTY 1 if \(\mathop {\lim }\limits_{h \to 0} {{f(h) - f(0)} \over {\sqrt {|h|} }}\) exists and is finite, and PROPERTY 2 if \(\mathop {\lim }\limits_{h \to 0} {{f(h) - f(0)} \over {{h^2}}}\) ex...
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25Limits Continuity And Differentiability
For \(a \in R,\,|a|\, > 1\), let $$\mathop {\lim }\limits_{n \to \infty } \left( {{{1 + \root 3 \of 2 + ...\root 3 \of n } \over {{n^{7/3}}\left( {{1 \over {{{(an + 1)}^2}}} + {1 \over {{{(an + 2)}^2}}} + ... + {1 \over {{{(an + n)}^2}}}} ...
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26Matrices And Determinants
Let x \(\in\) R and let \(P = \left[ {\matrix{
1 & 1 & 1 \cr
0 & 2 & 2 \cr
0 & 0 & 3 \cr
} } \right]\), \(Q = \left[ {\matrix{
2 & x & x \cr
0 & 4 & 0 \cr
x & x & 6 \cr
} } \right]\) and R = PQP\(-\)1, w...
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27Matrices And Determinants
Suppose
det\(\left| {\matrix{ {\sum\limits_{k = 0}^n k } & {\sum\limits_{k = 0}^n {{}^n{C_k}{k^2}} } \cr {\sum\limits_{k = 0}^n {{}^n{C_k}.k} } & {\sum\limits_{k = 0}^n {{}^n{C_k}{3^k}} } \cr } } \right| = 0\)
holds for some p...
det\(\left| {\matrix{ {\sum\limits_{k = 0}^n k } & {\sum\limits_{k = 0}^n {{}^n{C_k}{k^2}} } \cr {\sum\limits_{k = 0}^n {{}^n{C_k}.k} } & {\sum\limits_{k = 0}^n {{}^n{C_k}{3^k}} } \cr } } \right| = 0\)
holds for some p...
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28Matrices And Determinants
$${P_1} = I = \left[ {\matrix{
1 & 0 & 0 \cr
0 & 1 & 0 \cr
0 & 0 & 1 \cr
} } \right],\,{P_2} = \left[ {\matrix{
1 & 0 & 0 \cr
0 & 0 & 1 \cr
0 & 1 & 0 \cr
} } \right],\,{P_3} = \left[ {\matrix{
0 & 1 & 0 ...
1 & 0 & 0 \cr
0 & 1 & 0 \cr
0 & 0 & 1 \cr
} } \right],\,{P_2} = \left[ {\matrix{
1 & 0 & 0 \cr
0 & 0 & 1 \cr
0 & 1 & 0 \cr
} } \right],\,{P_3} = \left[ {\matrix{
0 & 1 & 0 ...
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29Parabola
Let the circle C1 : x2 + y2 = 9 and C2 : (x \(-\) 3)2 + (y \(-\) 4)2 = 16, intersect at the points X and Y. Suppose that another circle C3 : (x \(-\) h)2 + (y \(-\) k)2 = r2 satisfies the following conditions :(i) centre of C3 is collinear ...
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30Parabola
Let the circles C1 : x2 + y2 = 9 and C2 : (x \(-\) 3)2 + (y \(-\) 4)2 = 16, intersect at the points X and Y. Suppose that another circle C3 : (x \(-\) h)2 + (y \(-\) k)2 = r2 satisfies the following conditions :(i) Centre of C3 is collinear...
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31Permutations And Combinations
Five persons A, B, C, D and E are seated in a circular arrangement. If each of them is given a hat of one of the three colours red, blue and green, then the number of ways of distributing the hats such that the persons seated in adjacent se...
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32Permutations And Combinations
Let |X| denote the number of elements in a set X. Let S = {1, 2, 3, 4, 5, 6} be a sample space, where each element is equally likely to occur. If A and B are independent events associated with S, then the number of ordered pairs (A, B) such...
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33Trigonometric Functions And Equations
For non-negative integers n, let$$f(n) = {{\sum\limits_{k = 0}^n {\sin \left( {{{k + 1} \over {n + 2}}\pi } \right)} \sin \left( {{{k + 2} \over {n + 2}}\pi } \right)} \over {\sum\limits_{k = 0}^n {{{\sin }^2}\left( {{{k + 1} \over {n + 2}}...
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34Trigonometric Functions And Equations
Let f(x) = sin(\(\pi\) cos x) and g(x) = cos(2\(\pi\) sin x) be two functions defined for x > 0. Define the following sets whose elements are written in the increasing order:X = {x : f(x) = 0}, Y = {x : f'(x) = 0}Z = {x : g(x) = 0}, W = {...
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35Trigonometric Functions And Equations
Let f(x) = sin(\(\pi\) cos x) and g(x) = cos(2\(\pi\) sin x) be two functions defined for x > 0. Define the following sets whose elements are written in the increasing order :X = {x : f(x) = 0}, Y = {x : f'(x) = 0}Z = {x : g(x) = 0}, W = ...
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36Vector Algebra
Let \(\overrightarrow a = 2\widehat i + \widehat j - \widehat k\) and \(\overrightarrow b = \widehat i + 2\widehat j + \widehat k\) be two vectors. Consider a vector c = \(\alpha\)\(\overrightarrow a\) + \(\beta\)\(\overrightarrow b\), $$...
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37Atoms And Nuclei
A free hydrogen atom after absorbing a photon of wavelength \(\lambda\)a gets excited from the state n = 1 to the state n = 4. Immediately after that the electron jumps to n = m state by emitting a photon of wavelength \(\lambda\)e. Let t...
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38Atoms And Nuclei
Suppose a \(_{88}^{226}Ra\) nucleus at rest and in ground state undergoes \(\alpha\)-decay to a \(_{86}^{222}Rn\) nucleus in its excited state. The kinetic energy of the emitted \(\alpha\) particle is found to be 4.44 MeV. $$_{86}^{222}Rn...
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39Dual Nature Of Radiation
A perfectly reflecting mirror of mass M mounted on a spring constitutes a spring-mass system of angular frequency \(\Omega\) such that \({{4\pi M\Omega } \over h} = {10^{24}}{m^{ - 2}}\) with h as Planck's constant. N photons of wavelength...
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40Electromagnetic Induction
A 10 cm long perfectly conducting wire PQ is moving with a velocity I cm/s on a pair of horizontal rails of zero resistance. One side of the rails is connected to an inductor L = 1 mH and a resistance R = 1\(\Omega\) as shown in figure. Th...
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41Electrostatics
An electric dipole with dipole moment \({{{p_0}} \over {\sqrt 2 }}(\widehat i + \widehat j)\) is held fixed at the origin O in the presence of a uniform electric field of magnitude E0.If the potential is constant on a circle of radius R cen...
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42Geometrical Optics
Three glass cylinders of equal height H = 30 cm and same refractive index n = 1.5 are placed on a horizontal surface as shown in figure. Cylinder I has a flat top, cylinder II has a convex top and cylinder III has a concave top. The radii ...
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43Geometrical Optics
A monochromatic light is incident from air on a refracting surface of a prism of angle 75\(^\circ\) and refractive index \({n_0} = \sqrt 3\). The other refracting surface of the prism is coated by a thin film of material of refractive ind...
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44Heat And Thermodynamics
A mixture of ideal gas containing 5 moles of monatomic gas and 1 mole of rigid diatomic gas is initially at pressure P0, volume V0, and temperature T0. If the gas mixture is adiabatically compressed to a volume \({{{V_0}} \over 4}\), then t...
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45Heat And Thermodynamics
If the process on one mole of monatomic ideal gas is as shown in the TV-diagram with \({P_0}{V_0} = {1 \over 3}R{T_0}\), the correct match is,
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46Heat And Thermodynamics
If the process carried out on one mole of monoatomic ideal gas is as shown in the PV-diagram with \({p_0}{V_0} = {1 \over 3}R{T_0}\), the correct match is,
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47Laws Of Motion
A block of mass 2M is attached to a massless spring with spring-constant k.This block is connected to two other blocks of masses M and 2M using two massless pulleys and strings. The accelerations of the blocks are a1, a2 and a3 as shown in ...
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48Motion
A ball is thrown from ground at an angle \(\theta\) with horizontal and with an initial speed u0. For the resulting projectile motion, the magnitude of average velocity of the ball up to the point when it hits the ground for the first time...
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49Rotational Motion
A thin and uniform rod of mass M and length L is held vertical on a floor with large friction. The rod is released from rest so that it falls by rotating about its contact-point with the floor without slipping. Which of the following statem...
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50Units And Measurements
An optical bench has 1.5 m long scale having four equal divisions in each cm. While measuring the focal length of a convex lens, the lens is kept at 75 cm mark of the scale and the object pin is kept at 45 cm mark. The image of the object p...
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