Haloalkanes and Haloarenes

The compound from which chlorobenzene cannot be prepared easily is

In $\text{S}_\text{N}1$ reaction, the alkyl halide that on hydrolysis produces racemic mixture is

$\text{C}-\text{Cl}$ bond in methyl chloride compared to $\text{C}-\text{Cl}$ bond in chlorobenzene is

The organometallic compound $\left(\mathrm{CH}_3\right)_3 \mathrm{CMgBr}$ on reaction with $\mathrm{D}_2 \mathrm{O}$ produces $\qquad$

Chlorobenzene reacts with bromine gas in the presence of Anhyd $\mathrm{AlBr}_3$ to yield p-Bromochlorobenzene. This reaction is classified as ____________

In the following scheme of reaction.

X, y and Z respectively are

A haloalkane undergoes $\mathrm{S}_{\mathrm{N}} 2$ or $\mathrm{S}_{\mathrm{N}} 1$ reaction depending on

Identify A, B and C in the sequence.
$$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Br} \underset{\text { Alc. }}{\stackrel{\mathrm{KCN}}{\longrightarrow}} A \stackrel{\mathrm{LiAlH}_4}{\longrightarrow} B \stackrel{\mathrm{HNO}_2}{\longrightarrow} C...

Which one of the following chlorohydrocarbon readily undergoes solvolysis?

In the following pairs of halogen compounds, which compound undergoes faster \(S_N 1\) reaction?

The order of reactivity of the compounds $$\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Br}, \mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}\left(\mathrm{C}_6 \mathrm{H}_5\right) \mathrm{Br}, \mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}\left(\mathrm{CH}_...

Peroxide effect is observed with the addition of \(\mathrm{HBr}\) but not with the addition of HI to unsymmetrical alkene because

Which of the following halide shows highest reactivity towards \(\mathrm{S}_{\mathrm{N}} 1\) reaction?

Which of the following halide undergoes hydrolysis on warming with water/aqueous \(\mathrm{NaOH}\) ?

The compound having longest C\(-\)Cl bond is

Tertiary alkyl halide is practically inert to substitution by $\mathrm{S}_{\mathrm{N}} 2$ mechanism because of

Which of the following statements is true is case of alkyl halides?

Toluene reacts with halogen in presence of iron (III) chloride giving ortho and para halo compounds. The reaction is