Solutions PYQs - Last 10 Years

Freezing point of a 4% aqueous solution of X is equal to freezing point of 12% aqueous solution of Y. If molecular weight of X is A, then molecular weight of Y is -

Molecules of benzoic acid (C6H5COOH) dimerise in benzene. 'w' g of the acid dissolved in 30 g of benzene shows a depression in freezing point equal to 2K. If the percentage association of the acid to form dimmer in the solution is 80, then ...

A solution is prepared by dissolving 0.6 g of urea (molar mass = 60 g mol–1) and 1.8 g of glucose (molar
mass = 180 g mol–1) in 100 mL of water at 27oC. The osmotic pressure of the solution is :
(R = 0.08206 L atm K–1
mol–1)

The freezing point of a diluted milk sample is found to be –0.2oC, while it should have been –0.5oC for pure milk. How much water has been added to pure milk to make the diluted sample?

K2Hgl4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is:

Liquids A and B form an ideal solution in the entire composition range. At 350 K, the vaapor pressures of pure A and pure B are 7 \(\times\) 103 Pa and 12 \(\times\) 103 Pa, respectively . The composition of the vapor in equilibriumwith...

Elevation in the boiling point for 1 molar solution of glucose is 2 K. The depression in the freezing point for 2 molal solution of glucose in the same solvent is 2 K. The relation between Kb and Kf is

At room temperature, a dilute solution of urea is prepared by dissolving 0.60 of urea in 360 g of water. If the
vapour pressure of pure water at this temperature is 35 mm Hg, lowering of vapour pressure will be.
(molar mass of urea = 60 g m...

1 g of a non-volatile non-electrolyte solute is dissolved in 100 g of two different solvents A and B whose
ebullioscopic constants are in the ratio of 1 : 5. The ratio of the elevation in their boiling points, $${{\Delta {T_b}(A)} \over {\D...

The mass of a non-volatile, non-electrolyte solute (molar mass = 50 g mol-1 ) needed to be dissolved in 114 g octane to reduce its vapour pressure to 75%, is :

Two 5 molal solutions are prepared by dissolving a non-electrolyte non-volatile solute separately in the solvents X and Y. The molecular weights of the solvents are Mx and My, respectively where Mx = \({3 \over 4}\) My. The relative lowerin...

For 1 molal aqueous solution of the following compounds, which one will show the highest freezing
point?

A solution is prepared by mixing 8.5 g of CH2Cl2 and 11.95 g of CHCl3 . If vapour pressure of CH2Cl2
and CHCl3 at 298 K are 415 and 200 mmHg respectively, the mole fraction of CHCl3 in vapour form is : (Molar mass of Cl = 35.5 g mol−1)

5 g of Na2SO4 was dissolved in x g of H2O. The change in freezing point was found to be
3.82oC. If Na2SO4 is 81.5% ionised,
the value of x
(Kf for water=1.86oC kg mol−1) is approximately :
(molar mass of S = 32 g mol−1 and that of Na = ...

The freezing point of benzene decreases by 0.450C when 0.2 g of acetic acid is added to 20g of benzene. If
acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be:
(Kf for benzene = 5.12 K...