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Haloalkanes and Haloarenes PYQs - Last 5 Years

JEE Main / Chemistry / Organic Chemistry / 98 recent questions

ChemistryOrganic Chemistry2022-2026

Practice 98 JEE Main Chemistry questions from Haloalkanes and Haloarenes. Use the year-wise and type-wise breakdown to prioritize recent PYQs, then continue into the question list below.

98
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Chemistry / Organic Chemistry
2022-2026
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Based on indexed question metadata
98
Last 5 Years
2022-2026
98
Last 10 Years
2017-2026

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98PYQs
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#2 Easy19
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Last 5 Years Haloalkanes and Haloarenes Questions

Showing 48 of 98 filtered questions.

1Haloalkanes And Haloarenes
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{CH}_2-\mathrm{Cl}\) is an example of allyl halide.
Reason (R) : Allyl halides are...
MCQ+4 / -12024
2Haloalkanes And Haloarenes
The final product A, formed in the following multistep reaction sequence is :
MCQ+4 / -12024
3Haloalkanes And Haloarenes
Example of vinylic halide is :
MCQ+4 / -12024
4Haloalkanes And Haloarenes
2-chlorobutane \(+\mathrm{Cl}_2 \rightarrow \mathrm{C}_4 \mathrm{H}_8 \mathrm{Cl}_2\) (isomers)
Total number of optically active isomers shown by \(\mathrm{C}_4 \mathrm{H}_8 \mathrm{Cl}_2\), obtained in the above reaction is _________.
INTEGER+4 / -12024
5Haloalkanes And Haloarenes
Given below are two statements:
Statement - I: High concentration of strong nucleophilic reagent with secondary alkyl halides which do not have bulky substituents will follow \(\mathrm{S}_{\mathrm{N}}{ }^2\) mechanism.
Statement - II: A sec...
MCQ+4 / -12024
6Haloalkanes And Haloarenes
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A : Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom.
Reason R : Phenols react with ...
MCQ+4 / -12024
7Haloalkanes And Haloarenes
Alkyl halide is converted into alkyl isocyanide by reaction with
MCQ+4 / -12024
8Haloalkanes And Haloarenes
The correct statement regarding nucleophilic substitution reaction in a chiral alkyl halide is ;
MCQ+4 / -12024
9Haloalkanes And Haloarenes
Which among the following halide/s will not show \(\mathrm{S_N 1}\) reaction:
(A) \(\mathrm{H}_2 \mathrm{C}=\mathrm{CH}-\mathrm{CH}_2 \mathrm{Cl}\)
(B) \(\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{Cl}\)
(C)
(D)
Choose the most appropri...
MCQ+4 / -12024
10Haloalkanes And Haloarenes
Identify B formed in the reaction.
\(\mathrm{Cl}-\left(\mathrm{CH}_2\right)_4-\mathrm{Cl} \xrightarrow{\text { excess } \mathrm{NH}_3} \mathrm{~A} \xrightarrow{\mathrm{NaOH}} \mathrm{B}+\mathrm{H}_2 \mathrm{O}+\mathrm{NaCl}\)
MCQ+4 / -12024
11Haloalkanes And Haloarenes
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Haloalkanes react with KCN to form alkyl cyanides as a main product while with $\mathrm{AgCN}$ form isocyanide as the...
MCQ+4 / -12024
12Haloalkanes And Haloarenes
Choose the halogen which is most reactive towards \(\mathrm{S}_{\mathrm{N}} 1\) reaction in the given compounds (A, B, C & D)
MCQ+4 / -12023
13Haloalkanes And Haloarenes
The correct order of reactivity of following haloarenes towards nucleophilic substitution with aqueous \(\mathrm{NaOH}\) is :

Choose the correct answer from the options given below:
MCQ+4 / -12023
14Haloalkanes And Haloarenes
Major product '\(\mathrm{P}\)' formed in the following reaction is:
MCQ+4 / -12023
15Haloalkanes And Haloarenes
For the reaction

The correct statement is
MCQ+4 / -12023
16Haloalkanes And Haloarenes
The correct order of melting points of dichlorobenzenes is
MCQ+4 / -12023
17Haloalkanes And Haloarenes
In the following halogenated organic compounds, the one with the maximum number of chlorine atoms in its structure is :
MCQ+4 / -12023
18Haloalkanes And Haloarenes
Match List I with List II

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MCQ+4 / -12023
19Haloalkanes And Haloarenes
Decreasing order towards SN 1 reaction for the following compounds is:
MCQ+4 / -12023
20Haloalkanes And Haloarenes
Identify the correct order for the given property for following compounds.

Choose the correct answer from the option given below :
MCQ+4 / -12023
21Haloalkanes And Haloarenes
The compound which will have the lowest rate towards nucleophilic aromatic substitution on treatment with OH\(^-\) is
MCQ+4 / -12023
22Haloalkanes And Haloarenes
The isomeric deuterated bromide with molecular formula \(\mathrm{C_4H_8DBr}\) having two chiral carbon atoms is
MCQ+4 / -12023
23Haloalkanes And Haloarenes
Number of moles of AgCl formed in the following reaction is _____________
INTEGER+4 / -12023
24Haloalkanes And Haloarenes
Assertion A : Hydrolysis of an alkyl chloride is a slow reaction but in the presence of NaI, the rate of the hydrolysis increases.
Reason R : I\(^{-}\) is a good nucleophile as well as a good leaving group.
In the light of the above stateme...
MCQ+4 / -12023
25Haloalkanes And Haloarenes
The major product formed in the Friedel-Craft acylation of chlorobenzene is
MCQ+4 / -12023
26Haloalkanes And Haloarenes
In the following reaction 'X' is
MCQ+4 / -12023
27Haloalkanes And Haloarenes

Find out the correct statement from the options given below for the above 2 reactions.
MCQ+4 / -12023
28Haloalkanes And Haloarenes
Compound from the following that will not produce precipitate on reaction with \(\mathrm{AgNO}_{3}\) is :
MCQ+4 / -12023
29Haloalkanes And Haloarenes
The pair from the following pairs having both compounds with net non-zero dipole moment is
MCQ+4 / -12023
30Haloalkanes And Haloarenes
Identify the correct order of reactivity for the following pairs towards the respective mechanism

Choose the correct answer from the options given below:
MCQ+4 / -12023
31Haloalkanes And Haloarenes

In the given conversion the compound A is :
MCQ+4 / -12022
32Haloalkanes And Haloarenes
Two isomers (A) and (B) with Molar mass 184 g/mol and elemental composition C, 52.2%; H, 4.9% and Br 42.9% gave benzoic acid and p-bromobenzoic acid, respectively on oxidation with KMnO4. Isomer 'A' is optically active and gives a pale yell...
MCQ+4 / -12022
33Haloalkanes And Haloarenes

The stable carbocation formed in the above reaction is
MCQ+4 / -12022
34Haloalkanes And Haloarenes

Considering the above reactions, the compound 'A' and compound 'B' respectively are :
MCQ+4 / -12022
35Haloalkanes And Haloarenes
Which among the following pairs of the structures will give different products on ozonolysis? (Consider the double bonds in the structures are rigid and not delocalized.)
MCQ+4 / -12022
36Haloalkanes And Haloarenes
Compound 'A' undergoes following sequence of reactions to give compound 'B'.
The correct structure and chirality of compound 'B' is
[where Et is \(\left.-\mathrm{C}_{2} \mathrm{H}_{5}\right]\)
MCQ+4 / -12022
37Haloalkanes And Haloarenes
Which one of the following compounds is inactive towards SN1 reaction?
MCQ+4 / -12022
38Haloalkanes And Haloarenes
The major product (P) in the reaction

is
MCQ+4 / -12022
39Haloalkanes And Haloarenes
The major product of the following reaction contains ____________ bromine atom(s).
INTEGER+4 / -12022
40Haloalkanes And Haloarenes

In the above reaction 'A' is
MCQ+4 / -12022
41Haloalkanes And Haloarenes
The major product in the given reaction is
MCQ+4 / -12022
42Haloalkanes And Haloarenes
The major product of the following reaction is :
MCQ+4 / -12022
43Haloalkanes And Haloarenes
Major product '\(\mathrm{B}\)' of the following reaction sequence is :
MCQ+4 / -12022
44Haloalkanes And Haloarenes
Halogenation of which one of the following will yield m-substituted product with respect to methyl group as a major product?
MCQ+4 / -12022
45Haloalkanes And Haloarenes
In the presence of sunlight, benzene reacts with Cl2 to give product, X. The number of hydrogens in X is _____________.
INTEGER+4 / -12022
46Haloalkanes And Haloarenes
The major product in the reaction
MCQ+4 / -12022
47Haloalkanes And Haloarenes
In the given reaction sequence, the major product 'C' is :
MCQ+4 / -12022
48Haloalkanes And Haloarenes

Consider the above reaction. The number of \(\pi\) electrons present in the product 'P' is __________.
INTEGER+4 / -12022