Basics of Organic Chemistry

The hydrocarbon with seven carbon atoms containing a neopentyl and a vinyl group
is :

The distillation technique most suited for separating glycerol from spent-lye in the soap industry is :

The absolute configuration of

is :

Which of the following compounds will exhibit geometrical isomerism?

In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of AgBr. The
percentage of bromine in the compound is: (at. Mass Ag = 108; Br = 80)

For the estimation of nitrogen, 1.4 g of organic compound was digested by Kjeldahl method and the
evolved ammonia was absorbed in 60 mL of M/10 sulphuric acid. The unreacted acid required 20 ml of M/10
sodium hydroxide for complete neutrali...

The order of stability of the following carbocations :

Identify the compound that exhibits tautomerism.

Out of the following, the alkene that exhibits optical isomerism is

The correct order of increasing basicity of the given conjugate bases (R = CH3) is

Arrange the carbanions, \({(C{H_3})_3}\overline C\), \(\overline C C{l_3}\) , \({(C{H_3})_2}\overline C H\), \({C_6}{H_5}\overline C H{}_2\) in order of their decreasing stability :

The IUPAC name of neopentane is

The number of stereoisomers possible for a compound of the molecular formula
CH3 - CH = CH - CH(OH) - Me is :

The alkene that exhibits geometrical isomerism is :

The electrophile, \({E^ \oplus }\) attacks the benzene ring to generate the intermediate \(\sigma -\)complex. Of the following, which \(\sigma -\)complex is lowest energy?

The absolute configuration of

The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC
system of nomenclature is

Which one of the following conformation of cyclohexane is chiral?

Presence of a nitro group in a benzene ring

Which of the following molecules is expected to rotate the plane of plane - polarized light?

Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche) of
2-fluoroethanol is

The \(IUPAC\) name of the compound shown below is :

The increasing order of stability of the following free radicals is

CH3Br + Nu- \(\to\) CH3 - Nu + Br- The decreasing order of the rate of the above reaction with nucleophiles (Nu–) A to D is
[Nu– = (A) PhO–, (B) AcO–, (C) HO–, (D) CH3O–]

Due to the presence of an unpaired electron, free radicals are:

The decreasing order of nucleophilicity among the nucleophiles

The reaction

is fastest when \(X\) is

The \(IUPAC\) name of the compound is

Rate of the reaction

is fastest when \(Z\) is

Consider the acidity of the carboxylic acids:
(a) PhCOOH
(b) o – NO2C6H4COOH
(c) p – NO2C6H4COOH
(d) m – NO2C6H4COOH
Which of the following order is correct?

Which of the following compound is not chiral?

Which of the following is the strongest base ?

Which one the following does not have sp2 hybridized carbon?

Which of the following will have meso-isomer also?

Amongst the following compounds, the optically active alkane having lowest molecular mass is

Among the following four structures \(i\) to \(iv,\)

it is true that

The general formula CnH2nO2 could be for open chain

The IUPAC name of CH3COCH(CH3)2 is

In the anion HCOO\(-\)
the two carbon-oxygen bonds are found to be of equal length. What is the reason for it?

A similarity between optical and geometrical isomerism is that

Racemic mixture is formed by mixing two

Which of the following does not show geometrical isomerism?

Which of the following compounds has wrong \(IUPAC\) name ?

Following types of compounds (as \(I, II\) )

are studied in terms of isomerism in :

Arrangement of (CH3)3C-, (CH3)2CH-, CH3-CH2- when attached to benzyl or an unsaturated group in increasing order of inductive effect is