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Electrochemistry

JEE Main 2026 (Online) 22nd January Morning Shift

INTEGER+4 / -12026

Consider the following electrochemical cell at 298 K


$\mathrm{Pt}\left|\mathrm{HSnO}_2^{-}(\mathrm{aq})\right| \mathrm{Sn}(\mathrm{OH})_6{ }^{2-}(\mathrm{aq})\left|\mathrm{OH}^{-}(\mathrm{aq})\right| \mathrm{Bi}_2 \mathrm{O}_3(\mathrm{~s}) \mid \mathrm{Bi}(\mathrm{s})$.


If the reaction quotient at a given time is $10^6$, then the cell EMF $\left(\mathrm{E}_{\text {cell }}\right)$ is


$\_\_\_\_$ $\times 10^{-1} \mathrm{~V}$ (Nearest integer).


Given the standard half-cell reduction potential as


\(\mathrm{E}_{\mathrm{Bi}_2 \mathrm{O}_3 / \mathrm{Bi}, \mathrm{OH}^{-}}^{\circ}=-0.44 \mathrm{~V} \text { and } \mathrm{E}_{\mathrm{Sn}(\mathrm{OH})_6^{2-} / \mathrm{HSnO}_2^{-}, \mathrm{OH}^{-}}^{\circ}=-0.90 \mathrm{~V}\)

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