JEE Main 2025 (Online) 4th April Evening Shift

Which among the following compounds give yellow solid when reacted with $\mathrm{NaOI} / \mathrm{NaOH}$ ?

Choose the correct answer from the options given below :

The IUPAC name of the following compound is:

In which pairs, the first ion is more stable than the second?

The correct order of basicity for the following molecules is :

A dipeptide, " $x$ " on complete hydrolysis gives " $y$ " and " $z$ ". " $y$ " on treatment with aq. $\mathrm{HNO}_2$ produces lactic acid. On the other hand " z " on heating gives the following cyclic molecule.

Based on the information gi...

Given below are two statements:Statement (I): For , all three possible structures may be drawn as follows.
Statement (II): Structure III is most stable, as the orbitals having the lone pairs are axial, where the lp – bp repulsion is minimum...

Consider the following plots of $\log$ of rate constant $\mathrm{k}(\log \mathrm{k})$ vs $\frac{1}{\mathrm{~T}}$ for three different reactions. The correct order of activation energies of these reactions is :

Half life of zero order reaction $\mathrm{A} \rightarrow$ product is 1 hour, when initial concentration of reactant is $2.0 \mathrm{~mol} \mathrm{~L}{ }^{-1}$. The time required to decrease concentration of A from 0.50 to $0.25 \mathrm{~mol...

' $X$ ' is the number of electrons in $t_{2 g}$ orbitals of the most stable complex ion among $\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{FeCl}_6\right]^{3-}, \quad\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_...

The correct order of $\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Ni}(\mathrm{CO})_4\right]$ and $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ complex species based on the number of unpaired electrons pr...

A metal complex with a formula $\mathrm{MCl}_4 \cdot 3 \mathrm{NH}_3$ is involved in $\mathrm{sp}^3 \mathrm{~d}^2$ hybridisation. It upon reaction with excess of $\mathrm{AgNO}_3$ solution gives ' $x$ ' moles of AgCl . Consider ' $x$ ' is e...

Consider the following molecule(X).

The major product formed when the given molecule $(X)$ is treated with $\mathrm{HBr}(1 \mathrm{eq})$ is :

Given below are two statements :
Statement (I) : Alcohols are formed when alkyl chlorides are treated with aqueous potassium hydroxide by elimination reaction.
Statement (II) : In alcoholic potassium hydroxide, alkyl chlorides form alkenes ...

The molar conductance of an infinitely dilute solution of ammonium chloride was found to be $185 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ and the ionic conductance of hydroxyl and chloride ions are 170 and $70 \mathrm{~S} \mathrm{~cm}...

$x \mathrm{mg}$ of $\mathrm{Mg}(\mathrm{OH})_2($ molar mass $=58)$ is required to be dissolved in 1.0 L of water to produce a pH of 10.0 at 298 K . The value of $x$ is ________ mg. (Nearest integer)
(Given : $\mathrm{Mg}(\mathrm{OH})_2$ is ...

Given below are two statements :
Statement (I) : The first ionisation enthalpy of group 14 elements is higher than the corresponding elements of group 13.
Statement (II) : Melting points and boiling points of group 13 elements are in genera...

The incorrect relationship in the following pairs in relation to ionisation enthalpies is :

The elements of Group 13 with highest and lowest first ionisation enthalpies are respectively :

Match List - I with List - II

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A toxic compound " A " when reacted with NaCN in aqueous acidic medium yields an edible cooking component and food preservative " B ". " B " is converted to " C " by diborane and can be used as an additive to petrol to reduce emission. "C" ...

Given below are two statements:
Statement (I) : Molal depression constant $\mathrm{K}_f$ is given by $\frac{\mathrm{M}_1 \mathrm{RT}_f}{\Delta \mathrm{~S}_{\mathrm{fus}}}$, where symbols have their usual meaning.
Statement (II) : $\mathrm{K...

Sea water, which can be considered as a 6 molar $(6 \mathrm{M})$ solution of NaCl , has a density of $2 \mathrm{~g} \mathrm{~mL}^{-1}$. The concentration of dissolved oxygen $\left(\mathrm{O}_2\right)$ in sea water is 5.8 ppm . Then the con...

The amount of calcium oxide produced on heating 150 kg limestone ( $75 \%$ pure) is
_________ kg. (Nearest integer)
Given: Molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ) of Ca-40, O-16, C-12

Consider the ground state of chromium atom $(Z=24)$. How many electrons are with Azimuthal quantum number $l=1$ and $l=2$ respectively ?

Consider the given data :
(a) $\mathrm{HCl}(\mathrm{g})+10 \mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{HCl} .10 \mathrm{H}_2 \mathrm{O} \Delta \mathrm{H}=-69.01 \mathrm{~kJ} \mathrm{~mol}^{-1}$
(b) $\mathrm{HCl}(\mathrm{g})+40 \...

Let A be the point of intersection of the lines $\mathrm{L}_1: \frac{x-7}{1}=\frac{y-5}{0}=\frac{z-3}{-1}$ and $\mathrm{L}_2: \frac{x-1}{3}=\frac{y+3}{4}=\frac{z+7}{5}$. Let B and C be the points on the lines $\mathrm{L}_1$ and $\mathrm{L}_...

Let the values of p , for which the shortest distance between the lines $\frac{x+1}{3}=\frac{y}{4}=\frac{z}{5}$ and $\overrightarrow{\mathrm{r}}=(\mathrm{p} \hat{i}+2 \hat{j}+\hat{k})+\lambda(2 \hat{i}+3 \hat{j}+4 \hat{k})$ is $\frac{1}{\sq...

Let $\mathrm{a}>0$. If the function $f(x)=6 x^3-45 \mathrm{a} x^2+108 \mathrm{a}^2 x+1$ attains its local maximum and minimum values at the points $x_1$ and $x_2$ respectively such that $x_1 x_2=54$, then $\mathrm{a}+x_1+x_2$ is equal to :

If $1^2 \cdot\left({ }^{15} C_1\right)+2^2 \cdot\left({ }^{15} C_2\right)+3^2 \cdot\left({ }^{15} C_3\right)+\ldots+15^2 \cdot\left({ }^{15} C_{15}\right)=2^m \cdot 3^n \cdot 5^k$, where $m, n, k \in \mathbf{N}$, then $\mathrm{m}+\mathrm{n}...

Let the product of $\omega_1=(8+i) \sin \theta+(7+4 i) \cos \theta$ and $\omega_2=(1+8 i) \sin \theta+(4+7 i) \cos \theta$ be $\alpha+i \beta$, $i=\sqrt{-1}$. Let p and q be the maximum and the minimum values of $\alpha+\beta$ respectively....

If $\alpha$ is a root of the equation $x^2+x+1=0$ and $\sum_\limits{\mathrm{k}=1}^{\mathrm{n}}\left(\alpha^{\mathrm{k}}+\frac{1}{\alpha^{\mathrm{k}}}\right)^2=20$, then n is equal to _________.

Let $f(x)+2 f\left(\frac{1}{x}\right)=x^2+5$ and $2 g(x)-3 g\left(\frac{1}{x}\right)=x, x>0$. If $\alpha=\int_1^2 f(x) \mathrm{d} x$, and $\beta=\int_1^2 g(x) \mathrm{d} x$, then the value of $9 \alpha+\beta$ is :

If a curve $y=y(x)$ passes through the point $\left(1, \frac{\pi}{2}\right)$ and satisfies the differential equation $\left(7 x^4 \cot y-\mathrm{e}^x \operatorname{cosec} y\right) \frac{\mathrm{d} x}{\mathrm{~d} y}=x^5, x \geq 1$, then at $...

Let for two distinct values of p the lines $y=x+\mathrm{p}$ touch the ellipse $\mathrm{E}: \frac{x^2}{4^2}+\frac{y^2}{3^2}=1$ at the points A and B . Let the line $y=x$ intersect E at the points C and D . Then the area of the quadrilateral ...

The centre of a circle C is at the centre of the ellipse $\mathrm{E}: \frac{x^2}{\mathrm{a}^2}+\frac{y^2}{\mathrm{~b}^2}=1, \mathrm{a}>\mathrm{b}$. Let C pass through the foci $F_1$ and $F_2$ of E such that the circle $C$ and the ellipse $E...

Let the domains of the functions $f(x)=\log _4 \log _3 \log _7\left(8-\log _2\left(x^2+4 x+5\right)\right)$ and $\mathrm{g}(x)=\sin ^{-1}\left(\frac{7 x+10}{x-2}\right)$ be $(\alpha, \beta)$ and $[\gamma, \delta]$, respectively. Then $\alph...

Let the sum of the focal distances of the point $\mathrm{P}(4,3)$ on the hyperbola $\mathrm{H}: \frac{x^2}{\mathrm{a}^2}-\frac{y^2}{\mathrm{~b}^2}=1$ be $8 \sqrt{\frac{5}{3}}$. If for H , the length of the latus rectum is $l$ and the produc...

If $\int \frac{\left(\sqrt{1+x^2}+x\right)^{10}}{\left(\sqrt{1+x^2}-x\right)^9} \mathrm{~d} x=\frac{1}{\mathrm{~m}}\left(\left(\sqrt{1+x^2}+x\right)^{\mathrm{n}}\left(\mathrm{n} \sqrt{1+x^2}-x\right)\right)+\mathrm{C}$ where C is the consta...

The sum of the infinite series $\cot ^{-1}\left(\frac{7}{4}\right)+\cot ^{-1}\left(\frac{19}{4}\right)+\cot ^{-1}\left(\frac{39}{4}\right)+\cot ^{-1}\left(\frac{67}{4}\right)+\ldots$. is :

Let $f$ be a differentiable function on $\mathbf{R}$ such that $f(2)=1, f^{\prime}(2)=4$. Let $\lim \limits_{x \rightarrow 0}(f(2+x))^{3 / x}=\mathrm{e}^\alpha$. Then the number of times the curve $y=4 x^3-4 x^2-4(\alpha-7) x-\alpha$ meets ...

Let the matrix $A=\left[\begin{array}{lll}1 & 0 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0\end{array}\right]$ satisfy $A^n=A^{n-2}+A^2-I$ for $n \geqslant 3$. Then the sum of all the elements of $\mathrm{A}^{50}$ is :

A line passing through the point $\mathrm{A}(-2,0)$, touches the parabola $\mathrm{P}: y^2=x-2$ at the point $B$ in the first quadrant. The area, of the region bounded by the line $A B$, parabola $P$ and the $x$-axis, is :

The axis of a parabola is the line $y=x$ and its vertex and focus are in the first quadrant at distances $\sqrt{2}$ and $2 \sqrt{2}$ units from the origin, respectively. If the point $(1, k)$ lies on the parabola, then a possible value of k...

Let m and $\mathrm{n},(\mathrm{m}<\mathrm{n})$, be two 2-digit numbers. Then the total numbers of pairs $(\mathrm{m}, \mathrm{n})$, such that $\operatorname{gcd}(m, n)=6$, is __________ .

A card from a pack of 52 cards is lost. From the remaining 51 cards, n cards are drawn and are found to be spades. If the probability of the lost card to be a spade is $\frac{11}{50}$, then n is equal to ________ .

If the sum of the first 20 terms of the series
$\frac{4 \cdot 1}{4+3 \cdot 1^2+1^4}+\frac{4 \cdot 2}{4+3 \cdot 2^2+2^4}+\frac{4 \cdot 3}{4+3 \cdot 3^2+3^4}+\frac{4 \cdot 4}{4+3 \cdot 4^2+4^4}+\ldots \cdot$ is $\frac{\mathrm{m}}{\mathrm{n}}$...

Consider two sets A and B, each containing three numbers in A.P. Let the sum and the product of the elements of A be 36 and p respectively and the sum and the product of the elements of B be 36 and $q$ respectively. Let d and D be the commo...

Let $\mathrm{A}=\{-3,-2,-1,0,1,2,3\}$ and R be a relation on A defined by $x \mathrm{R} y$ if and only if $2 x-y \in\{0,1\}$. Let $l$ be the number of elements in $R$. Let $m$ and $n$ be the minimum number of elements required to be added i...

Let the mean and the standard deviation of the observation $2,3,3,4,5,7, a, b$ be 4 and $\sqrt{2}$ respectively. Then the mean deviation about the mode of these observations is :

Let the three sides of a triangle ABC be given by the vectors $2 \hat{i}-\hat{j}+\hat{k}, \hat{i}-3 \hat{j}-5 \hat{k}$ and $3 \hat{i}-4 \hat{j}-4 \hat{k}$. Let $G$ be the centroid of the triangle $A B C$. Then $6\left(|\overrightarrow{\math...