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JEE Main 2022 (Online) 27th June Morning Shift

JEE Main / 90 questions

2026Mon, Jun 27, 2022 3:30 AM90 PYQs
1Aldehydes Ketones And Carboxylic Acids
'A' and 'B' respectively are:
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2Aldehydes Ketones And Carboxylic Acids
Which of the following reactions will yield benzaldehyde as a product?



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3Basics Of Organic Chemistry
Total number of possible stereoisomers of dimethyl cyclopentane is ____________.
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4Biomolecules
L-isomer of a compound 'A' (C4H8O4) gives a positive test with [Ag(NH3)2]+. Treatment of 'A' with acetic anhydride yields triacetate derivative. Compound 'A' produces an optically active compound (B) and an optically inactive compound (C) o...
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5Chemical Bonding And Molecular Structure
Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in List-II and select the most appropriate option.

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6Chemical Equilibrium
2NOCl(g) \(\rightleftharpoons\) 2NO(g) + Cl2(g)
In an experiment, 2.0 moles of NOCl was placed in a one-litre flask and the concentration of NO after equilibrium established, was found to be 0.4 mol/L. The equilibrium constant at 30$$^\circ...
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7Chemical Kinetics And Nuclear Chemistry
The rate constant for a first order reaction is given by the following equation:
\(\ln k = 33.24 - {{2.0 \times {{10}^4}\,K} \over T}\)
The activation energy for the reaction is given by ____________ kJ mol\(-\)1. (In nearest integer) (Give...
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8Chemistry In Everyday Life
Match List - I with List - II.

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9Compounds Containing Nitrogen
Given below are two statements :
Statement I : In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen atom.
Statement II : The group is migrated in Hofmann degrada...
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10Coordination Compounds
Which of the following will have maximum stabilization due to crystal field?
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11Coordination Compounds
Acidified potassium permanganate solution oxidises oxalic acid. The spin-only magnetic moment of the manganese product formed from the above reaction is ____________ B.M. (Nearest integer)
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12D And F Block Elements
The number of statements correct from the following for Copper (at. no. 29) is/are ____________.
(A) Cu(II) complexes are always paramagnetic.
(B) Cu(I) complexes are generally colourless
(C) Cu(I) is easily oxidized
(D) In Fehling solution...
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13Electrochemistry
The limiting molar conductivities of NaI, NaNO3 and AgNO3 are 12.7, 12.0 and 13.3 mS m2 mol\(-\)1, respectively (all at 25\(^\circ\)C). The limiting molar conductivity of AgI at this temperature is ____________ mS m2 mol\(-\)1.
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14Environmental Chemistry
Given below are two Statements:
Statement I : Classical smog occurs in cool humid climate. It is a reducing mixture of smoke, fog and sulphur dioxide.
Statement II : Photochemical smog has components, ozone, nitric oxide, acrolein, formalde...
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15Haloalkanes And Haloarenes
The major product of the following reaction is :
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16Isolation Of Elements
Match List-I with List-II

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17Isolation Of Elements
Which of the following is structure of a separating funnel?
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18P Block Elements
Match List - I with List - II.

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19P Block Elements
Heating white phosphorus with conc. NaOH solution gives mainly :
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20Periodic Table And Periodicity
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : The ionic radii of O2\(-\) and Mg2+ are same.
Reason (R) : Both O2\(-\) and Mg2+ are isoelectronic species.
In the li...
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21Polymers
Match List - I with List - II

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22S Block Elements
Addition of H2SO4 to BaO2 produces :
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23S Block Elements
BeCl2 reacts with LiAlH4 to give :
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24Solid State
Metal deficiency defect is shown by Fe0.93O. In the crystal, some Fe2+ cations are missing and loss of positive charge is compensated by the presence of Fe3+ ions. The percentage of Fe2+ ions in the Fe0.93O crystals is __________. (Nearest ...
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25Solutions
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : At 10\(^\circ\)C, the density of a 5 M solution of KCl [atomic masses of K & Cl are 39 & 35.5 g mol\(-\)1 respectivel...
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26Solutions
2 g of a non-volatile non-electrolyte solute is dissolved in
200 g of two different solvents A and B whose ebullioscopic constants are in the ratio of 1 : 8. The elevation in boiling points of A and B are in the ratio \({x \over y}\) (x :...
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27Some Basic Concepts Of Chemistry
Two elements A and B which form 0.15 moles of A2B and AB3 type compounds. If both A2B and AB3 weigh equally, then the atomic weight of A is _____________ times of atomic weight of B.
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28Structure Of Atom
If the uncertainty in velocity and position of a minute particle in space are, 2.4 \(\times\) 10\(-\)26 (m s\(-\)1) and 10\(-\)7 (m) respectively. The mass of the particle in g is ____________. (Nearest integer)
(Given : h = 6.626 $$\times$...
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29Surface Chemistry
Match List-I with List-II

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30Thermodynamics
Match List-I with List-II.

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313d Geometry
If two straight lines whose direction cosines are given by the relations \(l + m - n = 0\), \(3{l^2} + {m^2} + cnl = 0\) are parallel, then the positive value of c is :
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323d Geometry
Let the mirror image of the point (a, b, c) with respect to the plane 3x \(-\) 4y + 12z + 19 = 0 be (a \(-\) 6, \(\beta\), \(\gamma\)). If a + b + c = 5, then 7\(\beta\) \(-\) 9\(\gamma\) is equal to ______________.
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33Area Under The Curves
Let
\({A_1} = \left\{ {(x,y):|x| \le {y^2},|x| + 2y \le 8} \right\}\) and
\({A_2} = \left\{ {(x,y):|x| + |y| \le k} \right\}\). If 27 (Area A1) = 5 (Area A2), then k is equal to :
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34Binomial Theorem
If the coefficient of x10 in the binomial expansion of \({\left( {{{\sqrt x } \over {{5^{{1 \over 4}}}}} + {{\sqrt 5 } \over {{x^{{1 \over 3}}}}}} \right)^{60}}\) is \({5^k}\,.\,l\), where l, k \(\in\) N and l is co-prime to 5, then k is eq...
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35Circle
A rectangle R with end points of one of its sides as (1, 2) and (3, 6) is inscribed in a circle. If the equation of a diameter of the circle is 2x \(-\) y + 4 = 0, then the area of R is ____________.
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36Complex Numbers
The area of the polygon, whose vertices are the non-real roots of the equation \(\overline z = i{z^2}\) is :
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37Definite Integration
The value of the integral \(\int\limits_{ - 2}^2 {{{|{x^3} + x|} \over {({e^{x|x|}} + 1)}}dx}\) is equal to :
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38Differential Equations
Let \({{dy} \over {dx}} = {{ax - by + a} \over {bx + cy + a}}\), where a, b, c are constants, represent a circle passing through the point (2, 5). Then the shortest distance of the point (11, 6) from this circle is :
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39Differential Equations
If \({{dy} \over {dx}} + {{{2^{x - y}}({2^y} - 1)} \over {{2^x} - 1}} = 0\), x, y > 0, y(1) = 1, then y(2) is equal to :
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40Differentiation
If \({\cos ^{ - 1}}\left( {{y \over 2}} \right) = {\log _e}{\left( {{x \over 5}} \right)^5},\,|y| < 2\), then :
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41Ellipse
Let the eccentricity of an ellipse \({{{x^2}} \over {{a^2}}} + {{{y^2}} \over {{b^2}}} = 1\), \(a > b\), be \({1 \over 4}\). If this ellipse passes through the point \(\left( { - 4\sqrt {{2 \over 5}} ,3} \right)\), then \({a^2} + {b^2}\) is...
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42Functions
Let f : R \(\to\) R be a function defined by \(f(x) = {{2{e^{2x}}} \over {{e^{2x}} + e}}\). Then $$f\left( {{1 \over {100}}} \right) + f\left( {{2 \over {100}}} \right) + f\left( {{3 \over {100}}} \right) + \,\,\,.....\,\,\, + \,\,\,f\left(...
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43Indefinite Integrals
If \(\int {{{({x^2} + 1){e^x}} \over {{{(x + 1)}^2}}}dx = f(x){e^x} + C}\), where C is a constant, then \({{{d^3}f} \over {d{x^3}}}\) at x = 1 is equal to :
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44Inverse Trigonometric Functions
\({\sin ^1}\left( {\sin {{2\pi } \over 3}} \right) + {\cos ^{ - 1}}\left( {\cos {{7\pi } \over 6}} \right) + {\tan ^{ - 1}}\left( {\tan {{3\pi } \over 4}} \right)\) is equal to :
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45Limits Continuity And Differentiability
Let a be an integer such that \(\mathop {\lim }\limits_{x \to 7} {{18 - [1 - x]} \over {[x - 3a]}}\) exists, where [t] is greatest integer \(\le\) t. Then a is equal to :
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46Mathematical Reasoning
The boolean expression \(( \sim (p \wedge q)) \vee q\) is equivalent to :
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47Matrices And Determinants
Let the system of linear equations \(x + 2y + z = 2\), \(\alpha x + 3y - z = \alpha\), \(- \alpha x + y + 2z = - \alpha\) be inconsistent. Then \(\alpha\) is equal to :
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48Matrices And Determinants
The positive value of the determinant of the matrix A, whose
Adj(Adj(A)) = \(\left( {\matrix{ {14} & {28} & { - 14} \cr { - 14} & {14} & {28} \cr {28} & { - 14} & {14} \cr } } \right)\), is _____________.
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49Parabola
A circle of radius 2 unit passes through the vertex and the focus of the parabola y2 = 2x and touches the parabola \(y = {\left( {x - {1 \over 4}} \right)^2} + \alpha\), where \(\alpha\) > 0. Then (4\(\alpha\) \(-\) 8)2 is equal to _______...
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50Permutations And Combinations
The number of ways, 16 identical cubes, of which 11 are blue and rest are red, can be placed in a row so that between any two red cubes there should be at least 2 blue cubes, is _____________.
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