Haloalkanes and Haloarenes
COMEDK / Chemistry / Organic Chemistry / 35 questions
ChemistryOrganic Chemistry35 PYQs
Practice 35 COMEDK Chemistry questions from Haloalkanes and Haloarenes. Use the year-wise and type-wise breakdown to prioritize recent PYQs, then continue into the question list below.
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Chemistry / Organic Chemistry
2020-2026
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2022-2026
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2017-2026
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Haloalkanes and Haloarenes Questions
Showing 35 of 35 questions on this page.
1Haloalkanes And Haloarenes
Two statements, Assertion and Reason are given. With reference to them, choose the correct option.
Assertion: Hydrolysis of 2-Bromo-2-methylpropane follows $S_N 1$ mechanism which involves 2 steps and the first step is:
Reason: The energy r...
Assertion: Hydrolysis of 2-Bromo-2-methylpropane follows $S_N 1$ mechanism which involves 2 steps and the first step is:
Reason: The energy r...
MCQ+1 / -02026
2Haloalkanes And Haloarenes
Identify the wrong statement from the following
MCQ+1 / -02026
3Haloalkanes And Haloarenes
Select the reagents needed to convert Benzene to 4-Bromophenylpropene in the correct sequential order.
(A). $\mathrm{Cl}_2 / \Delta$
(B). $\left(\mathrm{CH}_3\right)_2-\mathrm{CHCl}$ /anhyd. $\mathrm{AlCl}_3$
(C). Alc. KOH
(D). $\mathrm{Br}...
(A). $\mathrm{Cl}_2 / \Delta$
(B). $\left(\mathrm{CH}_3\right)_2-\mathrm{CHCl}$ /anhyd. $\mathrm{AlCl}_3$
(C). Alc. KOH
(D). $\mathrm{Br}...
MCQ+1 / -02026
4Haloalkanes And Haloarenes
With reference to the two statements Assertion and Reason, choose the correct option.
Assertion: The order of reactivity towards $\mathrm{S}_{\mathrm{N}} 1$ reaction is: $\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2 \mathrm{Br}>\left(\mathrm{CH}...
Assertion: The order of reactivity towards $\mathrm{S}_{\mathrm{N}} 1$ reaction is: $\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2 \mathrm{Br}>\left(\mathrm{CH}...
MCQ+1 / -02026
5Haloalkanes And Haloarenes
Identify the final product $[Z]$ formed when Chlorobenzene undergoes the given series of reactions:
MCQ+1 / -02025
6Haloalkanes And Haloarenes
Identify the compound which gives an optically active haloalkane on reaction with $\mathrm{H}_2$ / Ni on heating.
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MCQ+1 / -02025
7Haloalkanes And Haloarenes
Which one of the following is a true statement with reference to reaction between 2- Bromo-2-methylpropane and aqueous KOH ?
MCQ+1 / -02025
8Haloalkanes And Haloarenes
Both reactions (i) and (ii) give the same compound X as the major product. Identify X
(i). 3-Methylbut-1-ene $+\mathrm{HCl} \rightarrow \mathrm{X}$
(ii). Neopentyl alcohol $+\mathrm{HCl}\left(\right.$ anh. $\left.\mathrm{ZnCl}_2\right) \rig...
(i). 3-Methylbut-1-ene $+\mathrm{HCl} \rightarrow \mathrm{X}$
(ii). Neopentyl alcohol $+\mathrm{HCl}\left(\right.$ anh. $\left.\mathrm{ZnCl}_2\right) \rig...
MCQ+1 / -02025
9Haloalkanes And Haloarenes
Which of the following haloalkanes will give more than one isomeric product, on being heated with alc. KOH ?
MCQ+1 / -02025
10Haloalkanes And Haloarenes
The correct order of reactivity of halogens with alkanes is :
MCQ+1 / -02025
11Haloalkanes And Haloarenes
Identify the reagents to be used to complete the given reaction.
MCQ+1 / -02025
12Haloalkanes And Haloarenes
Toluene when reacted with $\mathrm{Cl}_2$ gas at 385 K forms a product X which undergoes further reaction with Sodium ethoxide to yield product Y . The structure of Y is ___________ .
MCQ+1 / -02025
13Haloalkanes And Haloarenes
Identify the incorrect statement.
MCQ+1 / -02025
14Haloalkanes And Haloarenes
Choose the incorrect statement from the following.
MCQ+1 / -02025
15Haloalkanes And Haloarenes
Which one of the following compounds when reacted with \(\mathrm{NaOH}\) (aq) undergoes Substitution Nucleophilic Bimolecular reaction with retention of configuration?
MCQ+1 / -02024
16Haloalkanes And Haloarenes
Arrange the following compounds in the increasing order of their reactivity when each of them is reacted with chloroethane / anhydrous AlCl\(_3\).
MCQ+1 / -02024
17Haloalkanes And Haloarenes
Identify the products C, D and F formed in the following sets of reactions.
MCQ+1 / -02024
18Haloalkanes And Haloarenes
Match the names of reactions given in Column I with the appropriate reactions given in Column II.
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MCQ+1 / -02024
19Haloalkanes And Haloarenes
Arrange the compounds \(\mathrm{A}, \mathrm{B}, \mathrm{C}\) and \(\mathrm{D}\) in the increasing order of their reactivity towards \(\mathrm{S_N}1\) reaction.
$$
\begin{aligned}
& \mathrm{A}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{...
$$
\begin{aligned}
& \mathrm{A}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{...
MCQ+1 / -02024
20Haloalkanes And Haloarenes
Identify the final product formed when Toluene undergoes a series of reactions with reagents given in the order:
(i) \(\mathrm{Cl}_2\) / Sunlight
(ii) \(\mathrm{H}_2 \mathrm{O} / 373 \mathrm{~K}\)
(iii) Acetophenone / \(\mathrm{OH^-}\) at $...
(i) \(\mathrm{Cl}_2\) / Sunlight
(ii) \(\mathrm{H}_2 \mathrm{O} / 373 \mathrm{~K}\)
(iii) Acetophenone / \(\mathrm{OH^-}\) at $...
MCQ+1 / -02024
21Haloalkanes And Haloarenes
The major product obtained in the following reaction is :
MCQ+1 / -02024
22Haloalkanes And Haloarenes
Arrange the following compounds in the decreasing order of reactivity towards electrophilic substitution reaction.
(I) Chlorobenzene
(II) Nitrobenzene
(III) Benzene
(IV) Isopropylbenzene
(I) Chlorobenzene
(II) Nitrobenzene
(III) Benzene
(IV) Isopropylbenzene
MCQ+1 / -02024
23Haloalkanes And Haloarenes
Consider the following reaction
\((\mathrm{CH}_3)_2 \mathrm{CHCH}_2 \mathrm{Br}+(\mathrm{CH}_3)_3 \mathrm{CCH}_2 \mathrm{Br} \xrightarrow[\Delta]{\mathrm{Na} \text { /dry ether }} \mathrm{X}+\mathrm{Y}+\mathrm{Z}\)
Identify the product whic...
\((\mathrm{CH}_3)_2 \mathrm{CHCH}_2 \mathrm{Br}+(\mathrm{CH}_3)_3 \mathrm{CCH}_2 \mathrm{Br} \xrightarrow[\Delta]{\mathrm{Na} \text { /dry ether }} \mathrm{X}+\mathrm{Y}+\mathrm{Z}\)
Identify the product whic...
MCQ+1 / -02024
24Haloalkanes And Haloarenes
Choose the incorrect statement from the following.
MCQ+1 / -02024
25Haloalkanes And Haloarenes
Arrange the following in the order of increasing reactivity towards \(\mathrm{SN}_{\mathrm{2}}\) reactions.
$$\begin{array}{ll}
\left(\mathrm{CH}_3\right)_3 \mathrm{CCH}_2 \mathrm{Br}(\mathrm{P}) ; & \\\mathrm{CH}_3\left(\mathrm{CH}_2\right...
$$\begin{array}{ll}
\left(\mathrm{CH}_3\right)_3 \mathrm{CCH}_2 \mathrm{Br}(\mathrm{P}) ; & \\\mathrm{CH}_3\left(\mathrm{CH}_2\right...
MCQ+1 / -02024
26Haloalkanes And Haloarenes
Identify the compounds A, B, C and D.
\(\text { 1,2,2,2-tetrachloroethane } \xrightarrow[\Delta]{\mathrm{Zn}}[\mathrm{A}]\)
[A] \(\xrightarrow[675 \mathrm{~K}]{\text { Fe tube }}\) [B] $$
\xrightarrow[\text { Conc. } \mathrm{H}_2 \mathr...
\(\text { 1,2,2,2-tetrachloroethane } \xrightarrow[\Delta]{\mathrm{Zn}}[\mathrm{A}]\)
[A] \(\xrightarrow[675 \mathrm{~K}]{\text { Fe tube }}\) [B] $$
\xrightarrow[\text { Conc. } \mathrm{H}_2 \mathr...
MCQ+1 / -02023
27Haloalkanes And Haloarenes
Which one of the following will undergo Nucleophilic substitution, by \(\mathrm{S}_{\mathrm{N}}{ }^1\) mechanism, fastest?
MCQ+1 / -02023
28Haloalkanes And Haloarenes
The reactions taking place with \(\mathrm{2- Phenyl-2-bromopropane}\) as the starting material is shown below. Identify [A] and [B] formed in the reaction.
$$
\mathrm{C}_6 \mathrm{H}_5-\mathrm{C}\left(\mathrm{CH}_3\right)_2^{-} \mathrm{Br} ...
$$
\mathrm{C}_6 \mathrm{H}_5-\mathrm{C}\left(\mathrm{CH}_3\right)_2^{-} \mathrm{Br} ...
MCQ+1 / -02023
29Haloalkanes And Haloarenes
Identify A, B and C.
MCQ+1 / -02023
30Haloalkanes And Haloarenes
In Friedal-Crafts alkylation reaction of phenol with chloromethane, the product formed will be
MCQ+1 / -02023
31Haloalkanes And Haloarenes
\(t\)-butyl chloride preferably undergo hydrolysis by
MCQ+1 / -02023
32Haloalkanes And Haloarenes
Alkyl halides undergoing SN2 reaction do inverse
MCQ+1 / -02022
33Haloalkanes And Haloarenes
The reaction \(\mathrm{ArN_2^ + C{l^ - }\buildrel {Cu/HCl} \over
\longrightarrow ArCl + {N_2} + CuCl}\) is called as
MCQ+1 / -02021
34Haloalkanes And Haloarenes
An alkyl halide reacts with alcoholic ammonia in
a sealed tube, the product formed will be
a sealed tube, the product formed will be
MCQ+1 / -02020
35Haloalkanes And Haloarenes
Benzene reacts with chlorine in sunlight to give a final product
MCQ+1 / -02020
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