Liquid Solution PYQs - Last 10 Years
AP EAPCET / Chemistry / Physical Chemistry / 54 recent questions
ChemistryPhysical Chemistry2016-2025
Practice 54 AP EAPCET Chemistry questions from Liquid Solution. Use the year-wise and type-wise breakdown to prioritize recent PYQs, then continue into the question list below.
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Last 10 Years Liquid Solution Questions
Showing 50 of 54 filtered questions.
1Liquid Solution
The following graph is obtained for an ideal solution containing a non-volatile solute $x$-and $y$-axis represent, respectively
MCQ+1 / -02025
2Liquid Solution
A solution is prepared by adding 124 g of ethylene glycol (molar mass $=62 \mathrm{~g} \mathrm{~mol}^{-1}$ ) to $x \mathrm{~g}$ of water to get 10 m solution. What is the value of $x$ (in g )?
MCQ+1 / -02025
3Liquid Solution
Elements $X$ and $Y$ form two non-volatile compounds ( $X Y$ and $X Y_3$ ). When 10 g of $X Y$ is dissolved in 50 g of ethanol, the depression in freezing point ( $\Delta T_f$ ) was 5.333 K . When 10 g of $X Y_3$ is dissolved in 50 g of eth...
MCQ+1 / -02025
4Liquid Solution
At $T(\mathrm{~K})$, the vapour pressure of water is $x \mathrm{kPa}$. What is the vapour pressure (in kPa ) of 1 molal solution containing non-volatile solute?
MCQ+1 / -02025
5Liquid Solution
What is the approximate molality of $10 \%(w / w)$ aqueous glucose solution?
(Molar mass of glucose $=180 \mathrm{~g} \mathrm{~mol}^{-1}$ )
(Molar mass of glucose $=180 \mathrm{~g} \mathrm{~mol}^{-1}$ )
MCQ+1 / -02025
6Liquid Solution
The van't Hoff factor for 0.5 m aqueous $\mathrm{CH}_2 \mathrm{FCOOH}$ solution is 1.075 . What is the experimentally observed $\Delta T_f$ (in K ) for this solution?
( $K_f=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ )
( $K_f=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ )
MCQ+1 / -02025
7Liquid Solution
An aqueous solution containing 0.2 g of a non volatile solute ' $A$ ' in 21.5 g of water freezes at 272.814 K . If the freezing point of water is 273.16 K , the molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ) of solute $A$ is $\left[\mathrm...
MCQ+1 / -02025
8Liquid Solution
At $T(\mathrm{~K})$, the vapour pressure of $x$ molal aqueous solution containing a non-volatile solute is $12.078 \mathrm{kPa}_{\mathrm{d}}$, The vapour pressure of pure water at $T(\mathrm{~K})$ is 12.3 kPa . What is the value of $x$ ?
MCQ+1 / -02025
9Liquid Solution
A solution of urea in water has a boiling point or $100.18^{\circ} \mathrm{C}$. What is the freezing point of the same solution, if $K_f$ and $K_b$ of water are 1.86 and 0.52 K kg $\mathrm{mol}^{-1}$.
MCQ+1 / -02025
10Liquid Solution
At $T(\mathrm{~K})$, the vapour pressure of pure benzene and toluene are 75 and 22 mm Hg respectively. 23.4 g of benzene and 64.4 g of toluene are mixed to form an ideal solution. If the vapours are in equilibrium with the liquid mixture, t...
MCQ+1 / -02025
11Liquid Solution
In aqueous glucose solution, the mole fraction of wate is 40 times to mole fraction of glucose. What is the weight percentage $(w / w)$ of glucose in the solution?
MCQ+1 / -02025
12Liquid Solution
Benzoic acid molecules undergo dimerisation in benzene. 2.44 g of benzoic acid when dissolved in 30 g of benzene caused depression in freezing point of 2 K . What is the percentage of association of it?
(Given $K_f\left(\mathrm{C}_6 \mathrm...
(Given $K_f\left(\mathrm{C}_6 \mathrm...
MCQ+1 / -02025
13Liquid Solution
The mole fractions of glucose and water in aqueous glucose solution are 0.0244 and 0.9756 respectively. What is the weight percentage $(w / w)$ of glucose in this solution?
MCQ+1 / -02025
14Liquid Solution
At $T(\mathrm{~K})$, the vapour pressure of an aqueous solution of a non-volatile solute, whose mole fraction is 0.02 is found to be 34.65 mm Hg . What is the vapour pressure (in mm Hg ) of pure water at the same temperature?
MCQ+1 / -02025
15Liquid Solution
At $298 \mathrm{~K}, 0.714$ moles of liquid $A$ is dissolved in 5.555 moles of liquid $B$. The vapour pressure of the resultant solution is 475 torr. The vapour pressure of pure liquid $A$ at the same temperature is 280.7 torr. What is the ...
MCQ+1 / -02025
16Liquid Solution
1.95 g of non-volatile and non-electrolyte solute dissolved in 100 g of benzene lowered the freezing point of it by 0.64 K .
The molar mass of the solute (in $\mathrm{g} \mathrm{mol}^{-1}$ )
$$ \left(K_f\left(\mathrm{C}_6 \mathrm{H}_6\right...
The molar mass of the solute (in $\mathrm{g} \mathrm{mol}^{-1}$ )
$$ \left(K_f\left(\mathrm{C}_6 \mathrm{H}_6\right...
MCQ+1 / -02025
17Liquid Solution
At 300 K vapour pressure of a pure liquid. ' $A$ ' is 70 mm Hg . It forms an ideal solution with another liquid ' $B$ '. The mole fraction of $B$ in the solution is 0.2 and total vapour pressure of solution is 84 mm Hg at same temperature. ...
MCQ+1 / -02025
18Liquid Solution
A centi molar solution of acetic acid is $50 \%$ dissociated at $27^{\circ} \mathrm{C}$. The osmotic pressure of the solution (in atm ) is $\left(R=0.083 \mathrm{~L}\right.$ atm $\left.\mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)$
MCQ+1 / -02025
19Liquid Solution
A solution containing 7.5 g of urea (molar mass $=60 \mathrm{~g} \mathrm{~mol}^{-1}$ ) in 1 kg of water freezes at the same temperature as another solution containing 15 g of solute $X$, in the same amount of water. The molar mass of $X\lef...
MCQ+1 / -02025
20Liquid Solution
248 g of ethylene glycol $\left(\mathrm{C}_2 \mathrm{H}_6 \mathrm{O}_2\right)$ is added to 200 g of water to prepare antifreeze. What is the molality of resultant solution?
$$ (\mathrm{C}=12 \mathrm{u} ; \mathrm{H}=1 \mathrm{u} ; \mathrm{O}...
$$ (\mathrm{C}=12 \mathrm{u} ; \mathrm{H}=1 \mathrm{u} ; \mathrm{O}...
MCQ+1 / -02025
21Liquid Solution
Two statements are given below
Statements I : Liquids $A$ and $B$ form a non-ideal solution with positive deviation. The interactions between $A$ and $B$ are weaker than $A-A$ and $B-B$ interactions.
Statements II : For an ideal solution $\...
Statements I : Liquids $A$ and $B$ form a non-ideal solution with positive deviation. The interactions between $A$ and $B$ are weaker than $A-A$ and $B-B$ interactions.
Statements II : For an ideal solution $\...
MCQ+1 / -02024
22Liquid Solution
At 300 K , the vapour prssures of $A$ and $B$ liquids are 500 and 400 mm Hg respectively. Equal moles of $A$ and $B$ are mixed to form an ideal solution. The mole fraction of $A$ and $B$ in vapour state is respectively
MCQ+1 / -02024
23Liquid Solution
At $T(\mathrm{~K})$ two liquids $A$ and $B$ form an ideal solution. The vapour pressures of pure liquid $A$ and $B$ at that temperature are 400 and 600 mm Hg respectively, If the mole fraction of liquid $B$ is 0.3 in the mixture, the mole f...
MCQ+1 / -02024
24Liquid Solution
Benzoic acid undergoes dimerisation in benzene. $x \mathrm{~g}$ of benzoic acid (molar mass $122 \mathrm{~g} \mathrm{~mol}^{-1}$ ) is dissolved in 49 g of benzene. The depression in freezing point is 1.12 K . If degree of association of ac...
MCQ+1 / -02024
25Liquid Solution
At 290 K , a vessel (I) contains equal moles of three liquids $(A, B, C)$. The boiling points of $A, B$ and $C$ are $350 \mathrm{~K}, 373 \mathrm{~K}$ and 308 K respectively. Vessel (I) is heated to 300 K and vapours were collected into ves...
MCQ+1 / -02024
26Liquid Solution
In water, which of the following gases has the highest Henry's law constant at 293 K ?
MCQ+1 / -02024
27Liquid Solution
At $300 \mathrm{~K}, 6 \mathrm{~g}$ of urea was dissolved in 500 mL of water. What is the osmotic pressure (in atm) of resultant solution?
$$ \begin{aligned} & \left(R=0.082 \mathrm{~L}^{\operatorname{atm~K}}{ }^{-1} \mathrm{~mol}^{-1}\righ...
$$ \begin{aligned} & \left(R=0.082 \mathrm{~L}^{\operatorname{atm~K}}{ }^{-1} \mathrm{~mol}^{-1}\righ...
MCQ+1 / -02024
28Liquid Solution
A solution was prepared by dissolving 0.1 mole of a non- volatile solute in 0.9 moles of water. What is the relative lowering of vapour pressure of solution?
MCQ+1 / -02024
29Liquid Solution
The following graph is obtained for vapour pressure (in atm) (on $Y$-axis) and $T$ (in K) (on $X$-axis) for aqueous urea solution and water. What is the boiling point (in K) of urea solution?
(Atmospheric pressure $=1 \mathrm{~atm}$ )
(Atmospheric pressure $=1 \mathrm{~atm}$ )
MCQ+1 / -02024
30Liquid Solution
Given below are two statements.
Statement I : Liquids $A$ and $B$ form a non-ideal solution with negative deviation. The interactions between $A$ and $B$ are weaker than $A-A$ and $B-B$ interactions.
Statement II : In reverse osmosis, the a...
Statement I : Liquids $A$ and $B$ form a non-ideal solution with negative deviation. The interactions between $A$ and $B$ are weaker than $A-A$ and $B-B$ interactions.
Statement II : In reverse osmosis, the a...
MCQ+1 / -02024
31Liquid Solution
The osmotic pressure of sea water is 1.05 atm . Four experiments were carried as shown in table. In which of the following experiments, pure water can be obtained in part-II of vessel.
$$
\begin{aligned}
&\text { Table }\\
&\begin{array}{...
$$
\begin{aligned}
&\text { Table }\\
&\begin{array}{...
MCQ+1 / -02024
32Liquid Solution
A non- volatile solute is dissolved in water. The $\Delta T_{\mathrm{b}}$ of resultant solution is 0.052 K . What is the freezing point of the solution ( in K )?( $K_b$ of water $=0.52 \mathrm{~K} \mathrm{kgmol}^{-1}$,$K_f$ of water $=1.86 ...
MCQ+1 / -02024
33Liquid Solution
200 g of $20 \% \frac{\mathrm{w}}{\mathrm{w}}$ urea solution is mixed with 400 g of $40 \% \frac{w}{w}$ urea solution. What is the weight percentage $\left(\frac{w}{w} \%\right)$ of resultant solution?
MCQ+1 / -02024
34Liquid Solution
The $\Delta T_b$ value for 0.01 m KCl solution is 0.01 K . What is the van't Hoff factor?
\(\left(K_b \text { for water }=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)\)
\(\left(K_b \text { for water }=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)\)
MCQ+1 / -02024
35Liquid Solution
At 293 K , methane gas was passed into 1 L . of water. The partial pressure of methane is 1 bar. The number of moles of methane dissolved in 1 L water is ( $K_{\mathrm{H}}$ of methane $=0.4 \mathrm{~K}$ bar)
MCQ+1 / -02024
36Liquid Solution
The molarity of one molal glucose solution having density of $1.2 \mathrm{~g} / \mathrm{mL}$ is
MCQ+1 / -02023
37Liquid Solution
6 g of urea (molar mass $=60 \mathrm{~g} \mathrm{~mol}^{-1}$ ) and 9 g of glucose $\left(\right.$ molar mass $\left.=180 \mathrm{~g} \mathrm{~mol}^{-1}\right)$ were dissolved in 35 g of water. The mass per cent of urea and glucose is respec...
MCQ+1 / -02023
38Liquid Solution
Which of the following does not belong to an ideal solution?
MCQ+1 / -02023
39Liquid Solution
What is the van't Hoff factor of ferric sulphate? (Assume $100 \%$ ionisation)
MCQ+1 / -02023
40Liquid Solution
Which of the following form an ideal solution?
I. Chloroethane and bromoethane
II. Benzene and toluene
III. \(n\)-hexane and \(n\)-heptane
IV. Phenol and aniline
I. Chloroethane and bromoethane
II. Benzene and toluene
III. \(n\)-hexane and \(n\)-heptane
IV. Phenol and aniline
MCQ+1 / -02022
41Liquid Solution
0.05 mole of a non-volatile solute is dissolved in 500 g of water. What is the depression in freezing point of resultant solution?
\(\left(K_f\left(\mathrm{H}_2 \mathrm{O}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)\)
\(\left(K_f\left(\mathrm{H}_2 \mathrm{O}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)\)
MCQ+1 / -02022
42Liquid Solution
At \(T(\mathrm{~K}) \times \mathrm{g}\) of a non-volatile solid (molar mass \(78 \mathrm{~g} \mathrm{~mol}^{-1}\)) when added to 0.5 kg water, lowered its freezing point by \(1.0^{\circ} \mathrm{C}\). What is \(x\) (in g)? (\(K_f\) of water...
MCQ+1 / -02022
43Liquid Solution
Assertion (A) Blood cells collapse when suspended in saline water.
Reason (R) Cell membrane dissolves in saline water.
Reason (R) Cell membrane dissolves in saline water.
MCQ+1 / -02022
44Liquid Solution
\(x \%(w / V)\) solution of urea is isotonic with \(4 \%\) \((w / V)\) solution of a non-volatile solute of molar mass \(120 \mathrm{~g} \mathrm{~mol}^{-1}\). The value of \(x\) is
MCQ+1 / -02022
45Liquid Solution
A solution containing 6.0 g of urea is isotonic with a solution containing 10 g of a non-electrolytic solute \(X\). The molar mass of X (in g \(\mathrm{mol}^{-1}\)) is
MCQ+1 / -02022
46Liquid Solution
If 500 mL of CaCl\(_2\) solution contains 3.01 \(\times\) 10\(^{22}\) chloride ions, molarity of the solution will be
MCQ+1 / -02021
47Liquid Solution
If the \(K_{\mathrm{H}}\) values for \(\operatorname{Ar}(g), \mathrm{CO}_2(g), \mathrm{HCHO}(g)\) and \(\mathrm{CH}_4(\mathrm{~g})\) respectively are \(40.39,1.67, 1.83 \times 10^{-5}\) and \(0.413\) , then identify the correct increasing o...
MCQ+1 / -02021
48Liquid Solution
The vapour pressure of a solvent decreased by
20 mm of Hg when a non-volatile solute was
added to the solvent. The mole fraction of the
solute in the solution is 0.5. What should be
the mole fraction of the solvent for the
decrease in the v...
20 mm of Hg when a non-volatile solute was
added to the solvent. The mole fraction of the
solute in the solution is 0.5. What should be
the mole fraction of the solvent for the
decrease in the v...
MCQ+1 / -02021
49Liquid Solution
If two liquids \(A\) and \(B\) form a minimum boiling azeotrope at some specific composition, then which statement among the following is correct?
MCQ+1 / -02021
50Liquid Solution
The molal elevation constant is the ratio of
elevation in boiling point to
elevation in boiling point to
MCQ+1 / -02021
