Three Dimensional Geometry

Let $\pi_1$ be the plane determined by the vectors $\hat{\mathbf{i}}+\hat{\mathbf{j}}$. $\hat{\mathbf{i}}+\hat{\mathbf{k}}$ and $\pi_2$ be the plane determined by the vectors $\hat{\mathbf{j}}-\hat{\mathbf{k}}, \hat{\mathbf{k}}-\hat{\mathbf{i}}$. Let $\mathbf{a}$ be a non-zero vector parallel to the line of intersection of the planes $\pi_1$ and $\pi_2$. If $\mathbf{b}=\hat{\mathbf{i}}+\hat{\mathbf{j}}-\hat{\mathbf{k}}$, then the angle between the vectors $\mathbf{a}$ and $\mathbf{b}$ is