Liquid Solution

' $x^{\prime} \mathrm{g}$ of urea (molar mass $60 \mathrm{gmol}^{-1}$ ) is completely dissolved in ' $y^{\prime} \mathrm{g}$ of pure water and the solution boiled at 373.202 K . If the boiling point of pure water at $1.01^3$ bar is 373.15 K , then $x: y$ is $\left(K_b\left(\mathrm{H}_2 \mathrm{O}\right)=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$