Chemical Kinetics

145. Rate constants in the following reaction are Reaction 1 :

\(A \xrightarrow{\text { Catalyst } 1} P_1, k_1=1 \mathrm{~s}^{-1}\)

Reaction 2 :

\(A \xrightarrow{\text { Catalyst } 2} P_2, k_2=0.1 \mathrm{~L} \mathrm{~mol}^{-1} \mathrm{~s}^{-1}\)

Reaction 3 :

\(A \xrightarrow{\text { Catalyst } 3} P_3, k_3=0.01 \mathrm{~L} \mathrm{~mol}^{-1} \mathrm{~s}^{-1}\)

The correct relations between the rate of the reactions at 1 M of $A$ are