Properties Of Triangles

In $\triangle A B C$, with usual notations, if $\mathrm{a}^4+\mathrm{b}^4+\mathrm{c}^4-2 \mathrm{a}^2 \mathrm{c}^2-2 \mathrm{c}^2 \mathrm{~b}^2=0$, then $\angle \mathrm{C}=\ldots$