Thermodynamics

$\mathrm{CH}_{4(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})} \longrightarrow \mathrm{CH}_3 \mathrm{Cl}_{(\mathrm{g})}+\mathrm{HCl}_{(\mathrm{g})}$

$3 \mathrm{H}_{2(\mathrm{~g})}+\mathrm{N}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{NH}_{3(\mathrm{~g})}$

$\mathrm{C}_2 \mathrm{H}_{2(\mathrm{~g})}+\frac{5}{2} \mathrm{O}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(l)}$

$\quad 2 \mathrm{C}_2 \mathrm{H}_{6(\mathrm{~g})}+7 \mathrm{O}_{2(\mathrm{~g})} \longrightarrow 4 \mathrm{CO}_{2(\mathrm{~g})}+6 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}$