Jee Advanced
Compounds Containing Nitrogen
JEE Advanced 2025 Paper 1 Online
MCQ+4 / -12025
The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.
| List–I | List–II |
|---|---|
| (P) Stephen reaction | (1) $$
\text { Toluene } \xrightarrow{\begin{array}{l}
\text { (i) } \mathrm{CrO}_2 \mathrm{Cl}_2 / \mathrm{CS}_2 \\
\text { (ii) } \mathrm{H}_3 \mathrm{O}^{+}
\end{array}}
$$ |
| (Q) Sandmeyer reaction | (2) $$
\text { Benzoic acid } \xrightarrow{\substack{\text { (i) } \mathrm{PCl}_5 \\ \text { (ii) } \mathrm{NH}_3 \\ \text { (iii) } \mathrm{P}_4 \mathrm{O}_{10}, \Delta}}
$$ |
| (R) Hoffmann bromamide degradation reaction | (3) $$
\text { Nitrobenzene } \xrightarrow{\begin{array}{l}
\text { (i) } \mathrm{Fe}, \mathrm{HCl} \\
\text { (ii) } \mathrm{HCl}, \mathrm{NaNO}_2 \\
(273-278 \mathrm{~K}), \mathrm{H}_2 \mathrm{O}
\end{array}}
$$ |
| (S) Cannizzaro reaction | (4) $$
\text { Toluene } \xrightarrow{\begin{array}{ll}
\text { (i) } \mathrm{Cl}_2 / \mathrm{h\nu}, \mathrm{H}_2 \mathrm{O} \\
\text { (ii) Tollen's reagent } \\
\text { (iii) } \mathrm{SO}_2 \mathrm{Cl}_2 \\ \text { (iv) } \mathrm{NH}_3 \end{array}}
$$ |
| (5) $$
\text { Aniline } \xrightarrow{\begin{array}{l}
\text { (i) }\left(\mathrm{CH}_3 \mathrm{CO}\right)_2 \mathrm{O}, \text { Pyridine } \\
\text { (ii) } \mathrm{HNO}_3, \mathrm{H}_2 \mathrm{SO}_4, 288 \mathrm{~K} \\
\text { (iii) aq. } \mathrm{NaOH}
\end{array}}
$$ |