Chemical Kinetics And Nuclear Chemistry

Match the rate expressions in LIST-I for the decomposition of $X$ with the corresponding profiles provided in LIST-II. $X_{\mathrm{s}}$ and $\mathrm{k}$ are constants having appropriate units.

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List-I	List-II
(I) rate $=\frac{\mathrm{k}[\mathrm{X}]}{\mathrm{X}_{\mathrm{s}}+[\mathrm{X}]}$ under all possible initial concentrations of $\mathrm{X}$	(P)
(II) rate $=\frac{k[X]}{X_{s}+[X]}$ where initial concentrations of $X$ are much less than $X_{s}$	(Q)
(III) rate $=\frac{k[X]}{X_{s}+[X]}$ where initial concentrations of $\mathrm{X}$ are much higher than $X_{s}$	(R)
(IV) rate $=\frac{k[X]^{2}}{X_{s}+[X]}$ where initial concentration of $X$ is much higher than $\mathrm{X}_{\mathrm{s}}$	(S)
	(T)