Comedk
Chemical Kinetics
COMEDK 2024 Morning Shift
For the reaction \(\mathrm{Cl}_{2(\mathrm{~g})}+2 \mathrm{NO}_{(\mathrm{g})} \rightarrow 2 \mathrm{NOCl}_{(\mathrm{g})}\), the following data was obtained:
.tg {border-collapse:collapse;border-spacing:0;}
.tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px;
overflow:hidden;padding:10px 5px;word-break:normal;}
.tg th{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px;
font-weight:normal;overflow:hidden;padding:10px 5px;word-break:normal;}
.tg .tg-baqh{text-align:center;vertical-align:top}
.tg .tg-amwm{font-weight:bold;text-align:center;vertical-align:top}
| Experiment No. | Initial concentration of \(\mathrm{Cl_2}\) (\(\mathrm{M}\)) | Initial concentration of \(\mathrm{NO}\) (\(\mathrm{M}\)) | Initial reaction rate (\(\mathrm{M}\)/min) |
|---|---|---|---|
| I | 0.15 | 0.15 | 0.60 |
| II | 0.30 | 0.15 | 1.20 |
| III | 0.15 | 0.3 | 2.40 |
| IV | 0.25 | 0.25 | 2.78 |
Identify the order of the reaction with respect to \(\mathrm{Cl}_2, \mathrm{NO}\) and the value of Rate constant.